alcohols Flashcards
what are the 3 main alcohol classifications
primary secondary tertiary
describe primary alcohols
the carbon atom with the hydroxyl group is attached to one other carbon atom
describe secondary alcohols
the carbon atom with the hydroxyl group is attached to two other carbon atom
describe tertiary alcohols
the carbon atom with the hydroxyl group is attached to three other carbon atom
alcohols with two hydroxyl groups are referred to as
diols
alcohols with three hydroxyl groups are referred to as
triols
are the boiling points of diols and triols high? Why?
high
strong hydrogen bonding
the more OH groups…
the higher the boiling point as ther is more hydrogen bonding which is strong and in increasing numbers requires more and more energy to break.
Why are large alcohol molecules less or not soluble
the london dispersion forces between the hydrocarbon parts of the alcohol molecules are stronger than hydrogen which makes it more difficult for large alcohol molecules to dissolve
why are smaller alcohol molecules more soluble
the presence of the OH group in both the alcohol and water molecules results in strong hydrogen bonding between the molecules
what is the functional group of the carboxylic acids
COOH
summarise neutralisation reaction of carboxylic acids
Carboxylic acids neutralise bases to form salts. The salt produced depends on the base reacted. The name of the salt always end in -oate