alcohals and phenols Flashcards

1
Q

alcohols are structural derivatives of

A

water

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2
Q

alcohols having 2 OH groups on adjacent carbons are called

A

glycols

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3
Q

the triol compound is known as

A

glycerol

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4
Q

glycerol is also called

A

glycerine

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5
Q

other names for methanol

A

wood spirit
carbinol
wood naphtha
Columbian spirit

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6
Q

conditions to prepare methanol from CO and hydrogen are

A

ZnO/ CrO3
450-500 degrees celsius
200 atm

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7
Q

other names for ehtanol

A

alcohol
grain alcohol
methyl carbinol
rectified spirit
absolute alcohol

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8
Q

necessary conditions for the fermentation are

A

aeration
dilution of solution
25-35 degrees Celsius
absence of any preservative

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9
Q

ethanol is prepared by the fermentation of

A

molasses
starch grains
fruit juices

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10
Q

formula of molasses is

A

C12H22O11

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11
Q

The enzyme used to convert molasses into glucose and fructose is

A

invertase

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12
Q

the enzyme used to convert glucose in to alcohol is

A

zymase

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13
Q

formula of starch

A

(C6H10O5)n

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14
Q

the reaction of water with starch gives

A

maltose

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15
Q

the formula of maltose is

A

C12H22O11

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16
Q

the enzyme used to convert starch in maltose is

A

diastase

17
Q

reaction of maltose with water gives

A

Glucose

18
Q

to convert maltose in glucose the enzyme used is

A

maltase

19
Q

the alcohol obtained by fermentation is only upto

A

12-14%

20
Q

rectified spirit is ___% alcohol

A

95

21
Q

absolute alcohol is obtained by the redistillation of rectified spirit in the presence of _____

A

CaO(quick lime)

22
Q

The purpose of quick lime during the redistillation of rectified spirit is

A

to absorb moisture

23
Q

methylated spirit contain _____% methanol

A

10

24
Q

compounds used for the denaturation of alcohols are

A

methanol
acetone
pyridine

25
Q

liquid alcohols are

A

from C1-C12

26
Q

solubility of alcohols

A

readily soluble in water
solubility decreases gradually

27
Q

the reaction involving C-O bond cleavage in alcohols are

A

nucleophilic substitution reactions

28
Q

The attacking specie in reactions involving C-O bond cleavage is

A

Nucleophile

29
Q

reactivity order of alcohols for nucleophilic substitution reaction

A

Tertiary > secondary > primary > Methanol

30
Q
A