acids and bases Flashcards

1
Q

litmus paper in acids

A

turns blue litmus paper red

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2
Q

litmus paper in bases

A

turns red litmus paper blue

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3
Q

Arrhenius acids

A

a substance that produces H + ions in aqueous solutions

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4
Q

Arrhenius base

A

a substance that produces OH- ions in aqueous solution

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5
Q

limitations of Arrhenius’s theory

A
  1. H+ does not exist in the water we always find H3O+
  2. only classifies acids and bases in water
  3. explains the basic properties of substances without OH- like NH3
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6
Q

bronsted lowry theory

A

refers to proton donors and proton acceptors

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7
Q

bronsted lowry acid

A

proton donor

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8
Q

bronsted lowry base

A

proton acceptor

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9
Q

amphoteric

A

can act as an acid or as a base

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10
Q

what does the strength of an electrolyte depend on?

A

on the extent of its dissociation into its component ions

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11
Q

strong electrolyte

A

completely dissociates into ions in solution

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12
Q

weak electrolyte

A

partially dissociates into ions in solution

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13
Q

what does it mean if the equilibrium lies to the right

A

acid is strong

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14
Q

what does it mean if the equilibrium lies to the left?

A

the acid is weak

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15
Q

what influences the degree to which an acid is strong or weak

A

the attraction between the anion of the acid and the hydrogen ion

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16
Q

what is the conc of water in water

A

55.5 mol

17
Q

why do we ignore water concentration in the equilibrium constant?

A

because the concentration of water in water is 55.5 mol and when we add acid, the conc of water barely changes

18
Q

high Ka

A

the equilibrium is lying on the right: strong acid

19
Q

low Ka

A

the equilibrium lies to the left: weak acid

20
Q

autoionisation of water

A

H20 + H20 ⇌ H3O+ +OH-

21
Q

neutral

A

[H3O+] = [OH-]

22
Q

acidic

A

[H3O+] > [OH-]

23
Q

basic

A

[H3O+] < [OH-]

24
Q

ionization constant for water

A

Kw = [H3O+] [OH-] = 10^-14 mol

25
Q

pH

A

pH= -log[H3O+]

26
Q

when does a substance behave as an acid

A

if it is a stronger acid than water: if its Ka is higher than Kw

27
Q

Ka higher than 1

A

strong acid

28
Q

Ka lower than 10^-14

A

it will behave as a base

29
Q

equation for strong acids

A

[H3O+] = Ca (initial)

30
Q

equation for weak acids

A

H3O+ = square root( Ka x Ca)

31
Q

equation for weak base

A

OH- = square root( Kb x Cb)

32
Q

lewis acid

A

electron pair acceptor

33
Q

lewis base

A

electron pair donor

34
Q

buffer

A

resists pH change by neutralizing added acid or added base

35
Q

what does a buffer consist of

A

of a weak acid and a conjugate base in similar concentrations or a weak base and its conjugate acid.

36
Q

what do we need when we want to buffer something

A

a substance with a pKa close to the pH we want to buffer

37
Q

Henderson Hasselbach Equation

A

pH = pKa + log [base]/[acid]

38
Q

blood pH

A

7.35- 7.45

39
Q

example of a buffer in biological fluids

A

carbonic acid/bicarbonate system:
CO2 + H2O ⇌ H2CO3