A2.5 Enthalpy And Entropy Flashcards
Entropy
A measure of the dispersal of energy in a system which is greater the more disordered a system
S
Every substance has positive entropy value
Sign of entropy changes depends on
How states change
Gas > liquid > solid
How moles change
More moles of gas = positive change
Calculating entropy change
^S = products - reactants
Consider moles
Feasibility of a reaction
Once started, it will carry on to completion without any energy being supplied to it
Feasibility depends on……
Temperature
Entropy
Enthalpy
A reaction is feasible when…..
Free energy change has a value of <= 0
^G
Free energy
^H - T^S
Calculate temperature at which feasibility changes
T = ^H / ^S
Feasibility straight line
Y = mx + c
^G = -^S T + ^H