A2.1 How Fast? Flashcards
Rate equation
Rate = k [A] [B]
Orders of reactants = power of
Zero order
Change in concentration of X has no effect on rate
First order
Concentration of X is directly proportional to rate
Second order
Change in rate is proportional to the square of change in conc
Gradient of line - concentration-time graph
Rate of reaction
Half life
Time taken for concentration to decrease by half
If half life is constant…..
First order
Using half life to calculate k
K = ln 2 /half life
Gradient - rate-conc graphs
First order - equal to rate constant
Collecting rates data - colorimeter
1)make up series of known concentration
2)measure absorbance of each
3)plot graph
Collecting rates data - continuous monitoring method
Gas collection - gas that can be measured
Mass loss over time - gas that can be released safely
Initial rates method
1)carry out several experiments changing conc each time
2)measure initial rate at T=0
3)measure time for visible change observed e.g. colour or precipitate
4)plot rate/conc graph
Rate determining step
Slowest step