6.4 corrosion m Flashcards
when does corrosion from on a metal?
whenever there is a difference in electrode potentials between parts of metal structure when in contact with an electrolyte
what do alkalis react with metals to create?
metallic salts (corrosion)
wat is used as a surface treatment for painting?
phosphoric acid solution
wat are ferrous metals subjected to but what is more vulnerable?
subject to damage but aluminium is more vulnerable to strong alkaline solutions than acids
corrosion should be distinguished from erosion but how is this done?
mechanical action
why does corrosion occur?
because of metals tendency to return to its original state
d noble metals corrode easily?
no because they are chemically pure in there natural state
where do all corrosive attacks start?
on the metal surface
what is the metal surface known as?
as electrolyte
what does the corrosion process involve?
two chemical changes
anodic and cathodic
what does the anode look like?
like it is being eten away
what happens in an anodic reaction?
electrolyte donates electrons into the internal circuit so the anode is oxidized
wat happens in a cathodic reaction?
receive electrons from anode and the electrons reduce the oxygen and water monocles into hydroxide ions and mixes with metal ions
what are examples of metals that produce corrosion products?
stainless steal
titanium
wen can the electrolyte easily penetrate and continue the corrosion process?
when the corrosion film is lose and prosperous
where does corrosion tend to form?
on less resistant surfaces but can also happen in boundary’s in between layers
what can corrosion in boundary layers result in?
pits and intergranular corrosion
what metals tend to lose electrons easily?
magnesium and aluminum
do metals corrode faster when thy lose more or fewer electrons?
when they lose more more easily
why may metals be corrosive resistant?
when they produce a passive oxide film on there surface
for corrosion to form what requirements must be met?
an electrical potential difference with the metal
a conductive path between the two areas of potential difference
some form of electrolyte or fluid covering the two areas
can corrosion be prevented?
no but can be controlled
what is one of the best way to control corrosion?
cleanliness
when does galvanic corrosion?
when two dissimilar metals make electrical contact in the presence of electrolyte
metals from what group corrode easier?
less noble groups
what metals will more actively corrode on the galvanic scale?
further apart on the galvanic scale
what is electrolytic corrosion?
when electrolyte and the flow of an electrical current between two metals
what does galvanic corrosion describe?
the interaction between two different metals
wat is an electrolytic corrosion caused by?
external source of current
wat does microbiological corrosion include?
actions of bacteria fungi or mold found in the fuel tanks
bacteria can be classified in to two category’s what are they?
aerobic
anaerobic
what does aerobic bacteria require?
require oxygen to live
how dos aerobic bacteria accelerate corrosion?
by oxidizing Sulphur to produce sulfuric acid
when does anerobic oxygen live?
can only survive when free oxygen is no present
what is fungi?
micro organisms that feed on organic materials
what slows the growth of microbes?
low humidity
what are ideal growth conditions for most micro organisms?
temperatures of 20 °C - 40 °C
relative humidity of 85% - 100%.
where does microbiological growth occur?
a the interface of water an fuel
what does the growth of fungus produce?
organic acids
alcohols
esters
Microbial corrosion can be minimized with a maintenance programmed that includes what?
A scheduled draining of water from the fuel tanks.
Inspections that look for a milky-white substance, indicating that microbial growth is present, followed by removing the microbial growth.
An application of biocide to prevent further growth.
wa are the two main areas susceptible to corrosion?
toilets and galleys
what is stress corosion?
growth of crack formation in corrosive environment
what can stress corrosion lead to?
unexpected and sudden failure of normally ductile metal alloys when subjected to tensile strength or cyclic loading
wat is a common place for stress corrosion?
between rivets in a stressed skin
what can sow the extent of stress corrosion?
dye penetrant
what is filiform corrosion?
form of oxygen-concentration cell corrosion or crevice corrosion that occurs on metal surfaces with an organic coating
how is filiform corrosion identified?
a worm like trace of corrosion produced beneath the paint film
when does filiform corrosion occur?
when the relative humidity of the air is 78% - 90% and the surface is slightly acidic
where does filiform corrosion start?
at breaches in the coating system as well as in fastener heads and extends along the surface of the painted sheet underneath the coating
what can happen if filiform corrosion is not removed?
can lead to intergranular corrosion
what is the most common type of corrosion on aluminum and magnesium?
pitting corrosion
wat is pitting corrosion?
a localized form of corrosion that produces holes in the material
what can holes in materials from pitting corrosion also cause?
act as stress risers and acid in forming stress croon
how is intergranular corrosion presented?
as cracking and tends to accelerate over time