4.1.2 Alkane reactions Flashcards
name 3 reasons why there is a lack of reactivity in an alkane
- C-H and C-C have strong sigma bonds
- the C-C bond is polar
- C-H have non-polar bonds
both polar and non polar are due to its electronegativity (likelyhood to gain e-)
when can complete combustion take place
when oxygen is in abundance
general complete combustion equation
alkane + oxygen -> carbon dioxide + water
how can you balance a combustion equation
- balance the C and H on the product side
2. balance the O on the reactant side
when does incomplete combustion take place. products which can be made
when not enough oxygen is available. makes CO or C
2 incomplete combustion equations
- alkane + oxygen -> carbon monoxide + water
2. alkane + oxygen -> carbon + water
what thing is needed for a reaction of alkane + halogen
UV light
general equation of alkane + halogen
alkane + halogen -> haloaklane + ( H+ halogen atom)
what is radical subsitution
A reaction containing very reactive radicals
3 steps of radical subsitution and what occurs using bromine + methane. explain what happens at each step
- initiation
this is when the halogen makes 2 radicals
Br2 -> Br* + Br* - propegation
here the radical reacts with the other reactant and this can cause 1 or 2 steps. as at first it may just make a halogen+halogen molecule and a alkane radical as it has lost a H
Ch4 + Br* -> Ch3* + HBr
Ch3* + Br2 -> Ch3Br + Br* - Termination
here you will add any radicals to eachother so they are molecules and unreactive