4.1 go over flashcards
electrophilic addition reactions can happen to
alkenes
what happens when an electrophilic reaction happens to an alkene- why does electrophilic reactions occur to alkenes
the alkene double bond opens up and atoms are added to the carbon atoms
- electrophilic reactions happen because the double bond had got plenty of electrons, its easily attracted by electrophiles.
- electrophiles are electron pair acceptors- they’re usually a bit short of electrons, so they’re attracted to areas where there are lost of them about.
- electrophiles include positively charged ions, like H+ and NO2+, and polar molecules ( since the delta+ atoms is attracted to places with lots of electrons
what does adding hydrogen to C=C bonds produce
alkanes
adding hydrogen to C=C bonds produce alkenes, what dos it need for this (conditions)
it needs a nickel catalyst and high temperature (150 degrees)
halogens react with alkenes to form…
dihaloalkanes
halogens react with alkenes to form dihaloalkanes, what sort of reaction is this
electrophilic addition
what can u use to test for C=C bonds and what colour does it turn
bromine water is used.
orange-> colourless
alcohols can be made by ____ ____ from alkenes
steam hydration
when converting alkenes to alcohols, what do u need?
- steam and pressure ( 60-70 atm)
- solid phosphoric (V) acid catalyst
why are carbocations more stable with more alkyl groups
because the alkyl groups feed electrons towards the positive charge.
what are useful things about polymers
-they’re very unreactive so food doesn’t react with the coasting on pans
what are unuseful things about polymers
because of their lack of reactivity, they are difficult to dispose of, most aren’t biodegradable
waste plastics can be buried, talk about this option
landfill: used when the plastic is: - difficult to separate - not in sufficient quantities to make separation financially worthwhile -too difficult technically to recycle
waste plastics can be reused, talk about this option
after sorting into different types:
- some plastics (e.g poly(propene)) can be recycled by melting and remolding them
- some plastics can be cracked into monomers, and these can be used as organic feedstock to make more plastics or other chemicals.
waste plastics can be burned, talk about this option
if recycling isn’t possible waste plastics can be burned-and the heat can be used to generate electricity.
- this process needs to be carefully controlled to reduce toxic gasses. e.g polymers containing chlorine (PVC)produce HCl when theyre burned- this has to be removed.
- waste gasses from the combustion are passed through scrubbers which can neutralize gasses such as HCl by allowing them to react with a base