4. Light emission Flashcards

1
Q

What does Emission mean?

A

Emission means to give off something, in our case light.

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2
Q

How can prism and optical grating participate in emission?

A

Prism or optical grating is used to decompose light emerging from the light source into its emission spectrum.

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3
Q

What is MONOCHROMATOR?

A

an optical component that selects a narrow wavelength range from the incident light by using either…

  • dispersion on a prism
  • or diffraction on an optical grating.
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4
Q

The entrance slit, prism or optical grating and exit slit are altogether called the __.

A

monochromator

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5
Q

Fill the gap

A
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6
Q

light intensity depends on the ___ (which device?), thus the corresponding width of the wavelength interval

A

width of the slit → The greater the slit-width, the greater the intensity

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7
Q

The role of The detector

A

It produces electric current proportional to intensity of light passing through the emission slit.

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8
Q

What is EMISSION SPECTRUM:?

A

emitted light intensity (J ) versus wavelength (􏰚).

→ It may be continuous, band or line spectrum

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9
Q

3 types of emission spectra

A

→ It may be continuous, band or line spectrum

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10
Q

Describe the spectrum produced by a prism

A

The spectrum produced by a prism is not linear, as dispersion is a nonlinear function of the wavelength.

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11
Q

Describe the spectrum produced by an optical grating

→ What is the disadvantage

A

has a linear wavelength dependence and hence a linear wavelength scale (Fig.3).

(The disadvantage of the grating over the prism is its low light utilization efficiency.)

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12
Q

Disadvantage of optical grating over prism

A

The disadvantage of the grating over the prism is its low light utilization efficiency.

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13
Q

What is the source of thermal radiation?

A

the thermal motion of the atoms, molecules, as they all have charges inside.

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14
Q

What is thermal radiation?

A

Electromagnetic radiation generated by the thermal motion of particles in matter.

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15
Q

Every material having nonzero absolute temperature (T> 0) emits___

A

thermal radiation

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16
Q

material having ___ emits thermal radiation.

A

nonzero absolute temperature (T> 0)

17
Q

What is LUMINESCENT RADIATION?

A

when energy of the radiation is provided by transition of electrons from the excited state to the ground state.

18
Q

3 ways to excite atoms and molecules

A
  1. by heating (thermo- luminescence, see flame photometer)
  2. by electric field (electro-luminescence, Hg vapor lamps)
  3. by radiation of higher energy visible or UV light (photoluminescence), etc.
19
Q

The role of spectrometer

A

device that registers emission spectra by plotting the intensity versus wavelength graph.

20
Q

How does a SPECTROMETER work?

A

Light from the light source enters through the entrance slit into the monochromator, where an optical grating decomposes it into its wavelength components.

→ The optical grating is rotated by a motor, thus different parts of the spectrum fall onto the exit slit.

→ The intensity of light selected by the slit is measured by a photodetector (photomultiplier or photodiode).

→ Primary electric current of the detector is amplified by the amplifier and is recorded by the X -Y plotter.

21
Q
  1. SPECTROMETER

Light from the (1)___ enters through the (2)___ into the (3)___, where an (4)___ decomposes it into its wavelength components.

→ The (5)___ is rotated by a motor, thus different parts of the spectrum fall onto the (6)___.

→ The intensity of light selected by the slit is measured by a (7)___ (photomultiplier or photodiode).

→ Primary electric current of the detector is amplified by the (8)___ and is recorded by the (9)___

A
  1. light source
  2. entrance slit
  3. monochromator
  4. optical grating
  5. optical grating
  6. exit slit
  7. photodetector
  8. amplifier
  9. X -Y plotter.
22
Q
  1. SPECTROMETER

Light from the (1)___ enters through the (2)___ into the (3)___, where an (4)___ decomposes it into its wavelength components.

→ The (5)___ is rotated by a motor, thus different parts of the spectrum fall onto the (6)___.

→ The intensity of light selected by the slit is measured by a (7)___ (photomultiplier or photodiode).

→ Primary electric current of the detector is amplified by the (8)___ and is recorded by the (9)___

A
  1. light source
  2. entrance slit
  3. monochromator
  4. optical grating
  5. optical grating
  6. exit slit
  7. photodetector
  8. amplifier
  9. X -Y plotter.
23
Q
  1. SPECTROMETER

Light from the light source enters through the entrance slit into the monochromator, where an optical grating (1)___

→ The optical grating is (2)____, thus (3)___ fall onto the exit slit.

→ (4)____ selected by the slit is measured by a photodetector (photomultiplier or photodiode).

→ (5)___ is amplified by the amplifier and is recorded by the X -Y plotter.

A
  1. decomposes it into its wavelength components.
  2. rotated by a motor
  3. different parts of the spectrum
  4. The intensity of light
  5. Primary electric current of the detector
24
Q

What is FLAME PHOTOMETER:?

A

A device in which the emission spectrum is produced after thermal excitation (by heating with a flame).

→ It is typically used for the determination of alkali metal concentration of solutions.

25
Q

FLAME PHOTOMETER

The energy required for the excitation of the atoms is provided by the ___

→ The equipment used in the measurement is used for the simultaneous determination of ___

A
  • the high temperature of the flame
  • Na, K, or Li concentrations of urine or blood plasma.
26
Q

FLAME PHOTOMETER

The sample solution is atomized with compressed air and___directly into the __

A
  • sprayed as an aerosol
  • flame of the burner
27
Q

FLAME PHOTOMETER

Light emitted by the thermally excited alkali metal atoms passes through a (1)____ with transmissions corresponding to (2)___

A
  • set of different band filters
  • the characteristic wavelength ranges of Na, K and Li.
28
Q

FLAME PHOTOMETER

Emitted light intensity, which is proportional to the concentration is detected by ___ that generate a corresponding electrical signal.

A

photosensors (photodiode)

29
Q

FLAME PHOTOMETER

(1)___ which is proportional to the concentration is detected by photosensors (photodiode) that generate (2)___.

→ (3)___ amplify these signals, and the relative concentration values (e.g., in mmol/l) are displayed.

A
  1. Emitted light intensity,
  2. a corresponding electrical signal
  3. Amplifiers
30
Q

FLAME PHOTOMETER

The energy required for the excitation of the atoms is provided by the high temperature of the flame___

→ The equipment used in the measurement is used for the simultaneous determination of ___

A
  • the high temperature of the flame
  • Na, K, or Li concentrations of urine or blood plasma.
31
Q

Light sources of different types.

A
  1. glow discharge bulb,
  2. high pressure sodium lamp,
  3. plasma globe,
  4. germicidal lamp and
  5. fluorescent coating.
32
Q

Fill the gap

A
33
Q

Fill the gap

A