3rd Six Weeks Flashcards

0
Q

How many types of acids are there?

A

2: containing oxygen & not containing oxygen

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1
Q

Why is are Roman numerals used?

A

Some metals can take more than one charge. The Roman numeral always indicates the charge on the metal in that compound. The Roman numeral does not tell you the number of metal atoms present in the compound.

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2
Q

Naming acids w/out oxygen

A
Ion Name:
•per\_\_\_ate
•\_\_\_ate
•\_\_\_ite
•hypo\_\_\_ite
Acid Name:
•per\_\_\_ic
•\_\_\_ic
•\_\_\_ous
•hypo\_\_\_ous
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3
Q

True or false: Electrons are almost never shared in pairs.

A

False: Electrons are almost always shared in pairs.

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4
Q

Covalent Bond

A

Two or more valence electrons are shared between two atoms

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5
Q

Single Bond

A

When one pair of electrons are shared between two atoms

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6
Q

The nucleus of the one is attracted to the _______ _________ of the other.

A

Valence electrons

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7
Q

Electronegativity

A

Attraction of one atom for the electrons of another atom (fluorine is the biggest); differences: The type of bond is found by determining the difference (subtract) of the electronegativities

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8
Q

Nonpolar covalent bond

A

When electrons are equally shared between two atoms

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9
Q

Polar covalent bond

A

When electrons are unequally shared

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10
Q

Dipole

A

When a bond or molecule has unequal sharing

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11
Q

Drawing Lewis structures for molecules

A
  1. Count up the number of valence electrons for each atom in the molecule
    -can do this easily by using the group number for each atom in the periodic table
    -adjust the valence electrons if you are drawing the structure for an ion
  2. Draw the atoms bonded together
    -usually the central atom is written first in a molecule, or the atoms in the molecule are written in the order in which they are
    -each bond contains two electrons
  3. Fill in the remaining valence electrons to give all atoms an octet of electrons. leaving the central atom for last
    A. If there are not enough electrons to complete all octets, use multiple bonds.
    B. If there are extra electrons, place them around
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12
Q

Exceptions to the Octet Rule

A
  1. Hydrogen and Helium- both can hold only two electrons
  2. Boron- often has only six electrons
  3. Free radicals- compounds with an odd number of electrons
  4. Atoms with “d” subshells- can hold more than eight electrons
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13
Q

True or False: each pair of bond electrons counts for both of the atoms in the bond

A

True

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14
Q

When an ion has a negative charge, what is required?

A

For this type of ion, surround the structure with brackets and write the charge on the ion outside.

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15
Q

What is VSEPR?

A

Valence shell electron pair repulsion (VSEPR) theory is a model used, in chemistry, to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms.

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16
Q

Carbonate

A

Percarbonate: CO4(charge of -2)
Carbonate: CO3(charge of -2)
Carbonite: CO2(charge of -2)
Hypocarbonite: CO(charge of -2)

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17
Q

Sulfate

A

Persulfate: SO5 (charge of -2)
Sulfate: SO4 (charge of -2)
Sulfite: SO3 (charge of -2)
Hyposulfite: SO2 (charge of -2)

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18
Q

Phosphate

A

Perphosphate: PO5(charge of -3)
Phosphate: PO4(charge of -3)
Phosphite: PO3(charge of -3)
Hypophosphite: PO2(charge of -3)

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19
Q

Chlorate

A

Perchlorate: ClO4(charge of -1)
Chlorate: ClO3(charge of -1)
Chlorite: ClO2(charge of -1)
Hypochlorite: ClO(charge of -1)

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20
Q

Iodate

A

Periodate: IO4(charge of -1)
Iodate: IO3(charge of -1)
Iodite: IO2(charge of -1)
Hypoiodite: IO(charge of -1)

21
Q

Acetate

A

Peracetate: C2H3O3(charge of -1)
Acetate: C2H3O2(charge of -1)
Acetite: C2H3O(charge of -1)

22
Q

Manganate

A

Permanganate: MnO4(charge of -1)
Manganate: MnO3(charge of -1)
Manganite: MnO2(charge of -1)
Hypomanganite: MnO(charge of -1)

23
Q

Bromate

A

Perbromate: BrO4(charge of -1)
Bromate: BrO3(charge of -1)
Bromite: BrO2(charge of -1)
Hypobromite: BrO(charge of -1)

24
Bicarbonate
Perbicarbonate: HCO4(charge of -1) Bicarbonate: HCO3(charge of -1) Bicarbonite: HCO2(charge of -1) Hypobicarbonate: HCO(charge of -1)
25
Oxalate
Peroxalate: C2O5(charge of -2) Oxalate: C2O4(charge of -2) Oxalite: C2O3(charge of -2) Hypoxalite: C2O2(charge of -2)
26
Chromate
Perchromate: CrO5(charge of -2) Chromate: CrO4(charge of -2) Chromite: CrO3(charge of -2) Hypochromite: CrO2(charge of -2)
27
Nitrate
Pernitrate: NO4(charge of -1) Nitrate: NO3(charge of -1) Nitrite: NO2(charge of -1) Hyponitrite: NO(charge of -1)
28
Arsenate
Perarsenate: AsO5(charge of -3) Arsentate: AsO4(charge of -3) Arsenite: AsO3(charge of -3) Hypoarsenite: AsO2(charge of -3)
29
Dichromate
Perdichromate: Cr2O8(charge of -2) Dichromate: Cr2O7(charge of -2) Dichromite: Cr2O6(charge of -2) Hypodichromite: Cr2O5(charge of -2)
30
Thiosulfate
Perthiosulfate: S2O4(charge of -2) Thiosulfate: S2O3(charge of -2) Thiosulfite: S2O2(charge of -2) Hypothiosulfite: S2O(charge of -2)
31
Bisulfate
Perbisulfate: HSO5(charge of -1) Bisulfate: HSO4(charge of -1) Bisulfite: HSO3(charge of -1) Hypobiosulfite: HSO2(charge of -1)
32
Sulfuric acid
Persulfuric acid: H2SO5 Sulfuric acid: H2SO4 Sulfurous acid: H2SO3 Hyposulfurous acid: H2SO2
33
Other Polyatomic Ions
``` Ammonium: NH4(charge of +1) Hydronium: H3O(charge of +1) Cyanide: CN(charge of -1) Peroxide: O2(charge of -2) Mercury (I): Hg2(charge of +2) Hydroxide: OH(charge of -1) ```
34
Carbonic acid
Percarbonic acid: H2CO4 Carbonic acid: H2CO3 Carbonous acid: H2CO2 Hypocarbonous acid: H2CO
35
Phosphoric acid
Perphosphoric acid: H3PO5 Phosphoric acid: H3PO4 Phosphorous acid: H3PO3 Hypophosphorous acid: H3PO2
36
Iodic acid
Periodic acid: HIO4 Iodic acid: HIO3 Iodous acid: HIO2 Hypoiodous acid: HIO
37
Chloric acid
Perchloric acid: HClO4 Chloric acid: HClO3 Chlorous acid: HClO2 Hypochlorous acid: HClO
38
Acetic acid
Peracetic acid: HC2H3O3 Acetic acid: HC2H3O2 Acetous acid: HC2H3O
39
Oxalic acid
Peroxalic acid: H2C2O5 Oxalic acid: H2C2O4 Oxalous acid: H2C2O3 Hypoxalous acid: H2C2O2
39
Manganic acid
Permanganic acid: HMnO4 Manganic acid: HMnO3 Manganous acid: HMnO2 Hypomanganous acid: HMnO
40
Bromic acid
Perbromic acid: HBrO4 Bromic acid: HBrO3 Bromous acid: HBrO2 Hypobromous acid: HBrO
41
Chromic acid
Perchromic acid: H2CrO5 Chromic acid: H2CrO4 Chromous acid: H2CrO3 Hypochromous acid: H2CrO2
42
Nitric acid
Pernitric acid: HNO4 Nitric acid: HNO3 Nitrous acid: HNO2 Hyponitrous acid: HNO
43
Arsenic acid
Perarsenic acid: H3AsO5 Arsenic acid: H3AsO4 Arsenous acid: H3AsO3 Hypoarsenous acid: H3AsO2
44
Dichromic acid
Perdichromic acid: H2Cr2O8 Dichromic acid: H2Cr2O7 Dichromous acid: H2Cr2O6 Hypodichromous acid: H2Cr2O5
45
Thiosulfuric acid
Perthiosulfuric acid: H2S2O4 Thiosulfuric acid: H2S2O3 Thiosulfurous acid: H2S2O2 Hypothiosulfurous acid: H2S2O
46
Binary Acids
-Must contain Hydrogen in the appropriate numbers to balance the negative charge of the anion -Prefix of hydro- -Suffix of -ic -Root word is nonmetal in shortened form Examples: •HCl: Hydrochloric acid •H2S: Hydrosulfuric acid
47
Shapes, sub-shapes, and bond angles
Shapes - Linear: 180 degrees; 2 sigma bond pairs & 0 lone pairs - Trigonal planar: 120 degrees; 3 sigma bond pairs & 0 lone pairs - Tetrahedral: 109.5 degrees; 4 sigma bond pairs & 0 lone pairs - Trigonal bypyramidal: 90 degrees & 120 degrees; 5 sigma bond pairs - Octahedral: 90 degrees; 6 sigma bond pairs & 0 lone pairs Sub-shapes - Bent (under trigonal planar): ~116 degrees; 2 sigma bond pairs & 1 lone pair - Trigonal pyramidal (under tetrahedral): ~107 degrees; 3 sigma bond pairs & 1 lone pair - Bent (under tetrahedral): ~105 degrees; 2 sigma bond pairs & 2 lone pairs - Unsymmetrical tetrahedron (under trigonal bipyramidal): 4 bond pairs & 1 lone pair - T-shaped (under trigonal bipyramidal): 3 bond pairs & 2 lone pairs - Linear (under trigonal bipyramidal): 2 bond pairs & 3 lone pairs - Square pyramidal (under octahedral): 5 bond pairs & 1 lone pair - Square planar (under octahedral): 4 bond pairs & 2 lone pairs
48
Binary Ionic Compounds using Transition Metals Rules
* Atoms combine in whole number ratios. | * The total charge on a compound must be zero.
49
How does symmetry play a role in determining polarity?
Symmetrical: Nonpolar Asymmetrical: Polar