3.6.2 Thermal physics Flashcards
What is the internal energy of a body equal to?
The sum of all of the kinetic energies and potential energies of all its particles
How are the kinetic and potential energies of a body distributed?
They are distributed randomly
What are the two ways of increasing the internal energy of a system?
- Do work on the system to transfer energy to it, such as moving its particles or changing its shape
- Increase the temperature of the system
What happens to the internal energy of a substance when its state is changed and why?
The internal energy changes, because the potential energy of the system changes, while the kinetic energy of the system is kept constant
Describe the state change as water boils.
The temperature increases up to 100ºC, after which the energy gained through heating the water is no longer used to increase the temperature, and therefore kinetic energy, but instead is used to break bonds between water molecules so it can change state to water vapour, so the potential energy is increased.
What does a horizontal line on a temperature - internal energy graph represent?
A boiling or melting point, where the substance is not increasing in temperature as its internal energy increases, as kinetic energy doesn’t change, but its potential energy increases as bonds are being broken between molecules, resulting in a state change
What is the specific heat capacity of a substance?
The amount of energy required to increase the temperature of 1kg of a substance by 1ºC/1K, without changing its state
What is the specific latent heat of a substance?
The amount of energy required to change the state of 1kg of material, without changing its temperature
What are the two types of specific latent heat?
- The specific latent heat of fusion, where a solid changes to a liquid
- The specific latent heat of vaporisation, where a liquid changes to a gas
What is the specific latent heat of fusion of a substance?
The amount of energy required to change 1kg of a solid to 1kg of liquid, without changing its temperature
What is the specific latent heat of vaporisation of a substance?
The amount of energy required to change 1kg of a liquid to 1kg of gas, without changing its temperature
What do the gas laws represent?
The experimental relationship between pressure, volume, and temperature for a fixed mass of gas
Why are the gas laws empirical in nature?
They are not based on theory but arose from observation and experimental evidence
What are the three gas laws?
Boyle’s Law, Charles’ Law, and the Pressure Law
What is Boyle’s Law?
For a fixed mass of gas, when temperature is constant, pressure and volume are inversely proportional, pV=k
What is Charles’ Law?
For a fixed mass of gas, when pressure is constant, volume is directly proportional to absolute temperature, V/T=k
What is the Pressure Law?
For a fixed mass of gas, when volume is constant, pressure is directly proportional to absolute temperature, p/T=k