3.2.2/3.12.2.5 Electromagnetic Radiation And Quantum Phenomena Flashcards

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1
Q

What is the photoelectric effect?

A

Photoelectrons are emitted from the surface of a metal after light above a certain frequency is shone on it

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2
Q

What is the threshold frequency?

A

The certain frequency for a type of metal that allows for the photoelectric effect to happen

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3
Q

How can threshold frequency be explained by the photon model of light?

A
  • EM waves travel in discrete packets called photons
  • Each electron can absorb a single photon, therefore a photoelectron is only emitted if the frequency is above the threshold frequency
  • If the intensity of the light is increased, and the frequency is above the threshold, more photoelectrons are emitted per second
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4
Q

Why can’t threshold frequency be explained by wave theory?

A

The wave theory suggests that any frequency of light should be able to cause photoelectric emission as the energy absorbed by each electron will gradually increase with each incoming wave

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5
Q

What is the work function of a metal?

A

The minimum energy required for electrons to be emitted from the surface of a metal

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6
Q

What is the stopping potential?

A

The potential difference you would need to apply across the metal to stop the photoelectrons with the maximum kinetic energy
Measuring it allows you to find the maximum kinetic energy of the released photoelectrons

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7
Q

What is ionisation?

A

Where electrons gain enough energy in an atom to be lost from it

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8
Q

What is excitation?

A

When an electron doesn’t gain sufficient energy to be lost from the atom, so it is temporarily promoted to an energy level further from the nucleus
It will then fall back to its original energy level and release the energy in the form of a photon of EM energy

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9
Q

Describe the fluorescent tube.

A
  • Mercury vapour inside low pressure tube
  • Mercury atoms are ionised (releasing more free electrons) and excited by colliding with free electrons
  • Mercury atoms de-excite to release ultraviolet photons
  • Fluorescent coating on inside of tube absorbs UV photons, exciting electrons in the coating, which de-excite to emit photons in the visible light spectrum
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10
Q

What is an electron volt?

A

The energy gained by one electron when passing though a potential difference of 1 volt

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11
Q

How do you convert from J to eV?

A

Divide by e (1.6x10^-19)

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12
Q

How do you convert from eV to J?

A

Multiply by e (1.6x10^-19)

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13
Q

What does each line in a line spectrum represent?

A

A different wavelength of light emitted

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14
Q

Why is a line spectrum not continuous?

A

It only contains discrete values of wavelength

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15
Q

What is the evidence for electrons in atoms only being able to transition between discrete energy levels?

A

Line spectra only show discrete values of wavelength, that the only photon energies emitted will correspond to

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16
Q

What are examples of light acting as a wave?

A

Diffraction and interference

17
Q

What is an example of light acting as a particle?

A

The photoelectric effect

18
Q

How and why does the amount of diffraction change when the momentum of the particle is changed?

A

When momentum increases, wavelength decreases, and therefore the amount of diffraction decreases, so the concentric rings of the interference pattern become closer (λ=h/mv)

19
Q

What is the de Broglie hypothesis?

A

All particles have a wave-like nature and a particle nature
λ=h/mv

20
Q

What must happen in order for experimental evidence to be validated?

A

Peer review

21
Q

How does electron diffraction provide experimental evidence for the de Broglie hypothesis?

A

It showed that electrons (particles) can undergo diffraction, which can only be experienced by waves

22
Q

Describe the electron diffraction experiment.

A
  • Electron gun accelerates electrons though a vacuum tube towards a crystal lattice
  • Electrons interact with the small gaps between the atoms to form a diffraction pattern on a fluorescent screen behind the crystal
23
Q

What is the relationship between the accelerating voltage and the de Broglie wavelength of electrons?

A

As the accelerating voltage increases, the speed of electrons increases, decreasing their de Broglie wavelength, decreasing the fringe spacing, following wave theory