3.5 Lipids Flashcards

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1
Q

What are the two most common types of lipid/

A

Fats and oils

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2
Q

Which elements do lipids contain?

A

Carbon, hydrogen, oxygen

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3
Q

What state are fats and oils typically at at room temp?

A

Fats = solid
Oils = liquid

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4
Q

Why are they non-polar

A

Their electrons are more evenly distributed

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5
Q

Why are they insoluble in water?

A

Because they have no charged areas (non-polar) so do not interact with the polar molecule water

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6
Q

What is the name for the type of molecule that lipids are?

A

Macromolecules
contain no repeating units (not monomers or polymers)

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7
Q

What are the 3 kinds of lipid?

A

Triglycerides
Phospholipids
Sterols

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8
Q

What are triglycerides made of?

A

Macromolecules made of 1 glycerol molecule and 3 fatty acids

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9
Q

What bonds are involved in triglycerides and what kind of reaction is it?

A

Forms strong ester bonds between each fatty acid and glycerol
Process known as esterification
CONDENSATION REACTION as water is removed during formation of each ester bond

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10
Q

What happens when triglycerides are broken down and what type of reaction is it?

A

3 water molecules need to be supplied to reverse the reaction
HYDROLYSIS REACTION

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11
Q

Example of a saturated fat

A

Butter

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12
Q

Example of an unsaturated fat

A

Oil

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13
Q

Where do saturated/unsaturated fats typically come from?

A

Saturated = animal fat
Unsaturated = plants and seeds etc

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14
Q

Functions of trigylcerides

A

Long term energy storage
Thermal insulation to prevent heat loss e.g. penguins
Protection of vital organs
Buoyancy for aquatic animals e.g. whales

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15
Q

Features of saturated fats

A

no double bonds
some evidence to suggest they can lead to coronary heart disease (solid at room temp)

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16
Q

Features of unsaturated fats

A

contain double bonds
cannot pack close together due to double bonds (liquid at room temperature)

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17
Q

1 double bond…

A

monounsaturated

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18
Q

2 or more double bonds…

A

polyunsaturated

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19
Q

What happens if you have too much of any fat…

A

Can lead to obesity

20
Q

What are phospholipids made from originally?

A

modified triglycerides

21
Q

What elements are phospholipids made from?

A

Carbon, hydrogen, oxygen and phosphorus

22
Q

Why are phosphate ions soluble in water?

A

They are negatively charged and so interact with the charges within the polar water molecule

23
Q

Structure of a phospholipid:

A

One of the fatty acid chains in a triglyceride is replaced with a phosphate group
Has a charged head and non-polar tails

24
Q

Difference between head and tails of a phospholipid

A

Head = negatively charged and so is hydrophilic (attracts water)
Tail = non-polar and so is hydrophobic (repels water)

25
Q

How does the dual structure affect how phospholipids interact with water?

A

Form a layer on top of water with phosphate heads IN the water with the tails STICKING OUT
Known as surface active agents (surfactants for shorts)

26
Q

Function of phospholipids:

A

Forming cell membranes

27
Q

How are phospholipids used in forming cell membranes?

A

Heads inside aqueous cytosol inside cell with tails pointing outwards,
Another layer of heads outside cell in aqueous outer environment with tails pointing inwards
Tails trapped between 2 layers of heads

28
Q

What type of molecule is glycerol

A

An alcohol (-OH)

29
Q

What type of molecule are fatty acids

A

Carboxylic acids (-COOH)

30
Q

Features of sterols

A

Also known of steroid alcohols
Not fats/oils
Complex alcohol molecules with 4 carbon ring structure with (OH) group at one end
Hydroxyl group is polar so is HYDROPHYLIC but rest of molecule is HYDROPHOBIC

31
Q

What kind of molecule is cholesterol?

A

Sterol

32
Q

Where in the body is cholesterol primarily manufactured?

A

Liver and intestines

33
Q

Function of cholesterol:

A

Cell membrane formation
positioned between phospholipids with hydroxyl group on the outskirts of membrane

34
Q

What happens to cholesterol and its function at low temps?

A

Adds stability to membrane and regulates fluidity by keeping membranes fluid at low temps

35
Q

What happens to cholesterol and its function at high temps?

A

Adds stability and regulates fluidity of membranes by stopping them from becoming too fluid at high temperatures
(move faster at room temps so require more stabilising)

36
Q

What else is cholesterol used to manufacture?

A

Bile
Vitamin D
Steroid hormones

37
Q

Roles of lipids:

A

Membrane formation and creation of hydrophobic barriers
Hormone production
Electrical insulation necessary for impulse transmission
Waterproofing e.g. birds’ feathers + plant leaves

38
Q

What else are lipids used for?

A

Long term energy storage
Thermal insulation to reduce heat loss e.g. penguins
Cushioning to protect vital organs like heart and kidneys
Buoyancy for aquatic animals e.g. whales

39
Q

Identification of lipids test:

A

EMULSION TEST:
Sample is mixed with ethanol
Mixed with water and shaken
IF a white emulsion forms, then lipids are present
IF solution remains clear, test is negative

40
Q

What factors make it difficult to find out the health impacts of one specific food type?

A

Difficult to isolate the impact of one nutrient
Believed that nutrients don’t work in isolation - combined effect
People may underestimate what they eat/forget
Difficult to know ingredients (eating out)

41
Q

Do saturated or unsaturated fats have high energy?

A

Both have high energy

42
Q

What can excess energy intake lead to?

A

Obesity

43
Q

How do ester bonds form?

A

Between hydroxyl group of glycerol and hydroxyl group of fatty acids during a condensation reaction producing water

44
Q

How are ester bonds broken?

A

Broken using water in a hydrolysis reaction which is the reverse reaction of their formation

45
Q

How does a lipid emulsion test work?

A

Dissolved in ethanol
Water added and shaken
Lipids are displaced by water which is more soluble in ethanol
Lipids left in suspension which forms a milky white emulsion if they are present