3.4 Electronegativity - bond polarity in covalent bonds Flashcards
Define electronegativity
The tendency of an atom to attract the electron density in a covalent bond
Define electron density
The way the negative charge is distributed in a molecule
How is electronegativity measured? When is it higher?
The Pauling scale (0-4)
- the greater the no., the greater the electronegativity
Factors that affect electronegativity
- nuclear charge
- atomic radius (nucleus to outer shell)
- e- shielding
Trend in electronegativity down a group
Decreases
- more e- shielding
- atoms get bigger
- same nuclear charge
Trend in electronegativity across a period
Increases
- nuclear charge increases
- same e- shielding
Where is the most electronegative? What atoms is it?
Top right-hand corner
-fluorine
What is polarity of covalent bonds?
The unequal sharing of electrons between covalently bonded atons
Polarity in covalent bonds between two of the same atom
Non-polar
- e- shared equally
- same electronegativity
- symmetrical
Polarity in covalent bonds between two different atoms
The greater the electronegativity difference, the greater the polarity of the covalent bond