3.3.6 Organic analysis Flashcards
Test for alkenes test
Shake with br2 water
Pos = orange to colourless
Haloalkanes test
Na0h (warm hno3 + agno3)
Presipitate of silver(halgen) that is a specific colour
Alcohols test
Accidifide potasium di cromate
Pos is orange to green witha secondary or a primary alchol
Aldehyde test
fehlings/tollens
Blu eto red ppt
Carboxylic acids test
Add nahco3
Co2 is given off
High resolution mass spectrometetry main points
Measureed to more decimal places
Allows you to workout molecular masses of parent ions
Isotopes of atoms do not have exact atomic masses
Can calculate the exact formular of molecules
Infrared spectrometry
bond always vibrating. Stronger bonds vibrate at high frequency.
Heavyer atoms means taht a bond vibrates slower
Every bind has a unique natural frequency in the infrared region
Infrared spectromrty rmethod
Add simple image
Shine infra red radiation at a sample and the bond adsorbed the energybmeaning it vibrates more
Only absorbeds the radiation that is vibrating at the same frequencyb as its natural frequency
The radiation missing is teh ones taht corrisspond to teh smaple
Graph for infrared spectrometery
Peak faces down - bottomest bits
Fingerprint region is unique to each molecule - area bellow 1500
0-h = alcohosl have a braud peak