3.3.1 - Intro to Organic Flashcards

1
Q

Define ‘molecular formula’

A

The actual number of atoms of each element in a molecule

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2
Q

In 3D structural formula, how do you show

a) bonds coming out
b) bonds going in
c) planar bonds?

A

a) bonds coming out - filled in wedge
b) bonds going in - dotted line
c) planar bonds - plain line

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3
Q

What is an methyl group?

A

-CH3

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4
Q

What is an ethyl group?

A

-C2H5

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5
Q

What is an propyl group?

A

-C3H8

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6
Q

What is an butyl group?

A

-C4H9

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7
Q

Nomenclature for alkanes? E.g. 2 carbons?

A

-ane suffix - ethane

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8
Q

Nomenclature for alkenes? E.g. 2 carbons?

A

-ene suffix - ethene

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9
Q

Nomenclature for halogenalkanes? E.g. 2 carbons?

A

haloethane (chloro/iodo/bromo/fluoro)

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10
Q

Nomenclature for alcohols? E.g. 2 carbons?

A

-ol suffix - ethanol

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11
Q

Nomenclature for ketones? E.g. 3 carbons?

A

-one suffix - propanone

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12
Q

Nomenclature for carboxylic acids? E.g. 3 carbons?

A

-oic acid suffix - Propanoic acid

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13
Q

Three types of structural isomerism?

A

Functional group
Chain
Positional

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14
Q

What is functional group isomerism?

A

Rearrangement of the atoms of the molecule into different functional groups (e.g. aldehyde/ketone)

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15
Q

What is chain isomerism?

A

Rearrangement of the carbon chain (e.g. branching)

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16
Q

What is positional isomerism?

A

Movement of the positional group (e.g. butan-1-ol/butan-2-ol).

17
Q

Define ‘homologous series’

A

Organic compound group with the same functional group but different carbon chain length

18
Q

Each member in a homologous series differs by _____

A

CH2

19
Q

Does carbon chain length significantly alter chemical reactivity?

A

No

20
Q

Does carbon chain length significantly alter physical properties?

A

Yes (melting/boiling points, solubility)

21
Q

What impact does branching of the carbon chain have on mpts?

A

Branching usually lowers mpt

22
Q

Define ‘stereoisomerism’

A

Same structural formula, different arrangement of atoms in space