(3.1.2) carbohydrates Flashcards
what are carbohydrates?
molecules composed of carbon, hydrogen and oxygen.
what are monosaccharides?
monosaccharides are the monomers from which larger carbohydrates are made.
what are examples of monosaccharides?
glucose, galactose and fructose.
what are isomers?
molecules with the same chemical formula but different arrangement of atoms and different properties.
(e.g. glucose has alpha-glucose and beta-glucose)
how are disaccharides formed?
by two monosaccharides chemically joined together by a condensation reaction, forming a glycosidic bond between the hydroxyl groups.
how can disaccharides break up?
by undergoing a hydrolysis reaction, which breaks the glycosidic bond and restores the original monosaccharides.
what are examples of disaccharides?
- maltose (two alpha-glucose)
- sucrose (glucose + fructose)
- lactose (glucose + galactose)
what are polysaccharides?
long, complex carbohydrates made of many monosaccharides chemically linked together by condensation reactions.
what are examples of polysaccharides?
- glycogen, starch (alpha-glucose polymers)
- cellulose (straight-chained beta-glucose polymer).
what are properties of glycogen?
- larger number of side branches providing lots of ends which can be easily hydrolysed to release glucose for respiration
- large and compact which maximises the amount of energy stored, and won’t affect the cell water potential
what are properties of starch?
- amylose is coiled which makes it very compact for more energy to be stored
- amylopectin is branched which provides lots of ends which can be easily hydrolysed to release glucose for respiration
- large + insoluble so it will not affect cell water potential
what are properties of cellulose?
- microfibrils held by hydrogen bonds which form strong cross linkages to provide strength to structure
- exerts inward pressure that stops the inflex of water, keeping cells rigid to maximise surface area for photosynthesis
how do you test for reducing sugars?
- add excess benedict’s to the test solution
- boil the mixture
blue > green/yellow/orange/red (if reducing sugar is present)
how do you test for non-reducing sugars?
- need a negative result for reducing sugars
- add hydrochloric acid and heat
- neutralise the acid with sodium hydroxide
- add benedict’s regent and boil
red precipitate if non-reducing sugar is initially present