2.31 - Solid Lattices Flashcards

1
Q

What are the 4 types of solid lattice?

A

Giant metallic lattices, giant ionic lattices, giant covalent lattices and discrete molecular lattices

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2
Q

What are metallic lattices composed of?

A

A regular arrangement of positive metal ions surrounded by delocalised electrons

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3
Q

What are the typical properties of giant metallic lattice compounds?

A

High melting and boiling temperatures, good electrical and thermal conductivity, malleability and ductility

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4
Q

What are giant ionic lattices composed of?

A

A regular arrangement of positive and negative ions

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5
Q

What are the typical properties of giant ionic lattice compounds?

A

Fairly high melting temperatures, brittleness, poor electrical conductivity when solid, but good when molten or in solution, and often soluble in water

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6
Q

What are giant covalent lattices sometimes known as?

A

Network covalent lattices

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7
Q

What do giant covalent lattices consist of?

A

Atoms linked to each other by covalent bonds

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8
Q

What are 4 of the most common giant covalent substances?

A

Diamond, graphite, graphene, and silicon (IV) oxide

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9
Q

What bonds, and how many, form for each carbon atom in diamond?

A

4 sigma bonds per carbon atom

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10
Q

What are the bond angles for diamond?

A

All 109.5 degrees

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11
Q

What are two properties of diamond?

A

High melting/boiling point, very hard

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12
Q

What type of structure does graphite have?

A

A layered structure

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13
Q

How many sigma bonds are there per carbon atom in graphite?

A

3

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14
Q

Where is the other electron?

A

In a p-orbital

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15
Q

What shape are the layers of graphite?

A

Hexagonal

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16
Q

What happens between the layers?

A

The p-orbitals overlap, producing a cloud of delocalised electrons

17
Q

What can graphite be used as?

A

A solid lubricant

18
Q

Why?

A

Because its layers can slide over each other

19
Q

Why can graphite conduct electricity?

A

Because there are delocalised electrons which can carry a charge

20
Q

What is graphene?

A

A one atom thick layer of graphite

21
Q

What are the common properties of molecular lattices?

A

Low melting and boiling points

22
Q

Why?

A

Because only London forces need to be overcome, which requires little energy