1.7 simple equilibrium and acid base reactions Flashcards
reversible reaction
a chemical reaction in which the products re-form the original reactants
Equilibrium
Forward reaction is equal to backwards reaction
Dynamic equilibrium
Rate of reactants being converted into products and back into reactants is constant
Le Chatelier’s Principle
If a change is made to a system in chemical equilibrium, the equilibrium shifts to oppose the change until a new equilibrium is reached
3 factors affecting equalibrium
Temp
Concentration
Pressure
How does decreasing temperature affect equilibrium position
Favour the exothermic reason so equilibrium shifts towards products of the exothermic reaction
How does increasing temperature affect equilibrium position
Increasing the temperature would favour the endothermic reaction, so the equilibrium will shift towards the products of the endothermic reaction.
How does increasing pressure affect equilibrium position
Favours side of the reaction with fewer moles of gas so position of equilibrium will move to that side
How does increasing concentration of the reactants affect the position of equilibrium
Equilibrium will shift to the right to increase the concentration of the products.
How do you work out units for Kc
Substitute units into the expression for Kc
Cancel common units and show the final units on a single line
What’s Kc
Equilibrium constant.
What effects Kc
only temperature
Calculations for Kc
Kc= (C)c (D)d/ (A)a (B)b
Acid
proton (H+) donor
Base
proton (H+) acceptor
Concentrated acid
An acid solution where there is a relatively large acid to water ratio
Dilute acid
Lots of water, small amount of acid in a given volume
Strong acid
fully dissociates in a solution
weak acid
partially dissociates in a solution
Apparatus needed for titration
H+= 10-^pH
PH scale
Expresses the acidity or alkalinity of a substance on a scale from 0-14 where 7 is neutral
Measuring hydrogen ions in a concentration.
How do you calc pH of a strong acid
Describe how to carry out a simple titration
- add acid to burette and use pipettes to add 25cm3 of alkali to a conical flask
- Add few drops of indicator in conical flask
- Record initial burette reading and slowly add acid to conical flask whilst swirling
4.when solution in conical flask changes colour to clearer stop adding acid and record final volume
5.calc total volume of acid added from burette.