4.1 steroisomerism Flashcards
Structural Isomerism
Same molecular formula, different atom arrangement.
Chain Isomerism
Isomers differ in straight or branched chains.
Stereoisomerism
Same structural formula, different spatial arrangement of atoms
E-Z Isomerism
Type of stereoisomerism in alkenes due to PI bond restricting rotation.
E-Isomer
Priority atoms on opposite sides of double bond.
Z-Isomer
Priority atoms on the same side of double bond.
Optical Isomerism
Different effects on plane polarized light.
Enantiomers
are non-superimposable mirror images of each other rotating the plane of polarised light in opposite directions
Chiral Centre
Atom in a molecule boned to 4 different atoms or groups.
Optical Activity
Occurs in molecules that possess chiral centres these molecules rotate the plane of polarised light.
Racemic Mixture
(equimolar solution of two enantiomers) shows no optical rotation