1.5.2 Bond Polarity (Physical Chemistry) Flashcards

1
Q

Electronegativity is

A

the power of an atom to attract the pair of electrons in a covalent bond towards itself

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2
Q

The electron distribution in a covalent bond between elements with different electronegativities will be

A

unsymmetrical

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3
Q

This phenomenon arises from

A

the positive nucleus’s ability to attract the negatively charged electrons, in the outer shells, towards itself

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4
Q

The Pauling scale is used to

A

assign a value of electronegativity for each atom

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5
Q

First three rows of the periodic table showing electronegativity values diagram

A
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6
Q

Fluorine is the

A

most electronegative atom on the Periodic Table, with a value of 4.0 on the Pauling Scale

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7
Q

Fluorine is best at

A

attracting electron density towards itself when covalently bonded to another atom

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8
Q

Electron distribution in the C-F bond of fluoromethane diagram

A
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9
Q

Attraction exists between

A

the positively charged protons in the nucleus and negatively charged electrons found in the energy levels of an atom

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10
Q

An increase in the number of protons leads to

A

an increase in nuclear attraction for the electrons in the outer shells

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11
Q

An increased nuclear charge results in

A

an increased electronegativity

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12
Q

The atomic radius is

A

the distance between the nucleus and electrons in the outermost shell

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13
Q

Electrons closer to the nucleus are

A

more strongly attracted towards its positive nucleus

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14
Q

Those electrons further away from the nucleus are

A

less strongly attracted towards the nucleus

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15
Q

Tn increased atomic radius results in

A

electronegativity decreases

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16
Q

Filled energy levels can

A

shield (mask) the effect of the nuclear charge causing the outer electrons to be less attracted to the nucleus

17
Q

The addition of extra shells and subshells in an atom will

A

cause the outer electrons to experience less of the attractive force of the nucleus

18
Q

Sodium (period 3, group 1) has higher electronegativity than caesium (period 6, group 1) as

A

it has fewer shells and therefore the outer electrons experience less shielding than in caesium

19
Q

An increased number of inner shells and subshells will result in

A

a decreased electronegativity

20
Q

Electronegativity varies across

A

periods and down the groups of the periodic table

21
Q

Down a group
- There is a decrease in

A

electronegativity

22
Q

Down a group
- The nuclear charge

A

increases as more protons are being added to the nucleus

23
Q

Down a group
- Each element has an extra filled electron shell, which

A

increases shielding

24
Q

Down a group
- The addition of the extra shells

A

increases the distance between the nucleus and the outer electrons resulting in larger atomic radii

25
Q

Down a group
- Overall, there is

A

decrease in attraction between the nucleus and outer bonding electrons

26
Q

Electronegativity decreases going down the groups of the periodic table diagram

A
27
Q

Across a period
- Electronegativity

A

increases

28
Q

Across a period
- The nuclear charge

A

increases with the addition of protons to the nucleus

29
Q

Across a period
- Shielding remains

A

relatively constant across the period as no new shells are being added to the atoms

30
Q

Across a period
- The nucleus has

A

an increasingly strong attraction for the bonding pair of electrons of atoms across the period of the periodic table

31
Q

Across a period
- The nucleus has an increasingly strong attraction for the bonding pair of electrons of atoms across the period of the periodic table, this results in

A

smaller atomic radii

32
Q

Electronegativity increases going across the periods of the Periodic Table diagram

A
33
Q
A