1.3 Covalent Bonding Flashcards
shape of beryllium chloride
linear
shape of H2O
bent
shape of boron trifluoride
triognal planar
electron pair repulsion theory
electron pairs are negatively charged and repel each other so are arranged to minimise repulsion and maximise separation
dative covalent bond
when an atom supplies both electrons in the formation of a covalent bond
when an atom supplies both electrons in the formation of a covalent bond
dative covalent bond
bonding pair of electrons
two electrons shared in a covalent bond
lone pair
held closer to the central atom, so they have a greater repulsion than bonding pairs
held closer to the central atom, so they have a greater repulsion than bonding pairs
lone pair
repulsion continuum
LP-LP greatest repulsion → LP-BP → BP-BP weakest repulsion
bonding/lone pair equation
electron pairs = (Number of electrons of the central atom + number of atoms attached) /2
2 BPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: linear
- molecule shape: linear
- angle: 180
- shape: Be-Cl-Be
3 BPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: trigonal planar
- molecule shape: trigonal planar
- angle: 120
- shape: pictured
4 BPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: tetrahedral
- molecule shape: tetrahedral
- angle: 109.5
- shape: pictured
5 BPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: trigonal bipyramidal
- molecule shape: trigonal bipyramidal
- angle: 90, 120, 180
- shape: pictured
6 BPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: octahedral
- molecule shape: octahedral
- angle: 90
- shape: pictured
2 BPs 2 LPs:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: tetrahedral
- molecule shape: bent angular
- angle: 104.5
- shape: pictured
3 BPs 1 LP:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: tetrahedral
- molecule shape: trigonal pyramidal
- angle: 107
- shape: pictured
4 BPs 2 LP:
- electron pair arrangement
- molecule shape
- angle in degrees
- shape
- electron pairs: octahedral
- molecule shape: square planar
- angle: 90
- shape: pictured
bond angle for lone paired atoms equation
109 - (2.5 x number of lone pairs)
what do to do electron number when there is a negative ion
add an electron
what do to do electron number when there is a positive ion
remove an electron
bond angle of BF3
90
shape of NH4^+
molecule is tetrahedral, electron pairs are tetrahedral
shape of NH3
molecule is pyramidal, electron pairs are tetrahedral
shape of AlH4^-
molecule is tetrahedral, electron pairs are tetrahedral
shape of SF6
molecule is octahedral, electron pairs are octahedral
shape of BF3
molecule is trigonal planar, electron pairs are trigonal planar
shape of BeCl2
molecule is linear, electron pairs are linear
shape of IF4^-
molecule is square planar, electron pairs are octahedral