1.1.7: Ionisation energies Flashcards

1
Q

Ionisation

A

where one electron is removed from the atom

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2
Q

Ionisation equation

A

e- on right hand side of equation

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3
Q

Ionisation energies

state

A

in gas phase

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4
Q

Ionisation energy

first

A

the energy required to remove an electron from every atom in a mole of atomic gas to produce a mole of unipositive gaseous ions

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5
Q

Factors affecting ionisation

3

A

shielding
nuclear charge
distance from the nucleus

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6
Q

How does shielding affect ionisation energy

A

more electrons between nucleus and outer electrons = lower nuclear charge
(+charge from nucleus decreased by more electrons in between)
so greater no. of electrons = lower ionisation energy

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7
Q

How does nuclear charge affect ionisation energy

A

more protons in nucleus = greater attraction of electron to nucleus
more energy needed to remove electron

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8
Q

How does distance from the nucleus affect ionisation energy

A

electrostatic attraction decreases w/ distance
less energy required to remove further away electrons
increase in distance, decrease in ionisation energy

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9
Q

Ionisation energy … down a group

why

A

decreases

atomic radius increases

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10
Q

Ionisation energy … across a period

why

A

increases

increase in proton number and nuclear charge

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11
Q

Exceptions

A

look at sub-shells

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12
Q

Electron repulsion impact on ionisation energy

A

easier to remove an electron from an orbital with 2 electrons in than 1 because the electrons repel each other

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