1.1.7: Ionisation energies Flashcards
Ionisation
where one electron is removed from the atom
Ionisation equation
e- on right hand side of equation
Ionisation energies
state
in gas phase
Ionisation energy
first
the energy required to remove an electron from every atom in a mole of atomic gas to produce a mole of unipositive gaseous ions
Factors affecting ionisation
3
shielding
nuclear charge
distance from the nucleus
How does shielding affect ionisation energy
more electrons between nucleus and outer electrons = lower nuclear charge
(+charge from nucleus decreased by more electrons in between)
so greater no. of electrons = lower ionisation energy
How does nuclear charge affect ionisation energy
more protons in nucleus = greater attraction of electron to nucleus
more energy needed to remove electron
How does distance from the nucleus affect ionisation energy
electrostatic attraction decreases w/ distance
less energy required to remove further away electrons
increase in distance, decrease in ionisation energy
Ionisation energy … down a group
why
decreases
atomic radius increases
Ionisation energy … across a period
why
increases
increase in proton number and nuclear charge
Exceptions
look at sub-shells
Electron repulsion impact on ionisation energy
easier to remove an electron from an orbital with 2 electrons in than 1 because the electrons repel each other