11.5 Reaction mechanisms Flashcards
Two ways a covalent bond can be broken
Homolytic fission
Heterolytic fission
Homolytic fission
Each of the bonded atoms takes one of the shared pair of electrons from the covalent bond
Heterolytic fission
One of the bonded atoms takes both of the electrons from the covalent bond
What is the product of homolytic fission
Radicals: an atom or group of atoms with impaired electrons
What are the products of heterolytic fission
Ions
Purpose of organic reaction mechanisms
Provide information on how a reaction takes place
When are ‘curly’ arrows used
To show the movement of a e- pair when bonds are broken or made by heterolytic fission
3 types of reaction and definition
Addition
Substitution
Elimination
Addition reaction
When two reactant molecules join together to form one product
Substitution reaction
An atom or group of atoms is replaced by a different atom or group of atoms
Elimination
A small molecule is removed from a larger molecule
Atom economy of an addition reaction
100%, only one product is made