11 The Behavior of Gases Flashcards
Boyle’s Law
states that for a given mass of gas at constant temperature, the volume of the gas varies inversely with pressure. The equation involves pressure-volume calculation, and two given pressures and volumes will be equivalent when multiplied (P1 x V1 = P2 x V2; 100 kPa’s at 1 L will be 50 kPa’s at 2 L.)
Charles’s law
states that the volume of a fixed mass of gas is directly proportional to its Kelvin temperature if the pressure is kept constant. The equation V1/T1 = V2/T2 is used to express this, where the ratios will always be equivalent. (1 L at 300^K, if turned to 600^K, would become 2 L.)
Be sure to use Kelvin in your equation!
The Ideal Gas Law
Allows one to find the moles of a gas at any given pressure, volume, and temperature. The usual form is this: P x V/ T x n = R, R is just a number, called the ideal gas constant
ideal gas constant
This number, R, is 8.31 (L x kPa)/(K x mol). The equation for the ideal Gas law is P x V/T x n = R OR P x V = n x R x T
It may be necessary to convert moles to kilograms if the amount of kilograms is what is asked for.
partial pressure
the contribution each gas in a mixture makes to the total pressure is the partial pressure of that gas.
In gas mixture the total pressure is the sum of the partial pressures.
Dalton’s law of partial pressures
at a constant volume and temperature, the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the component gases. Ptotal = P1 + P2 + P3