10. Spectroscopy Flashcards

1
Q

as you move from Red to violet what happens to the wavelength and frequency

A

wavelength decreases
frequency increases

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2
Q

what is the wavelength equation

A

wavelength = speed of light / frequency

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3
Q

single bonds appear on what side of the spectrum

A

right side

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4
Q

what are the wavenumbers that single bonds appear in

A

<1500

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5
Q

double bonds appear from what wavenumbers

A

1600-1850

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6
Q

triple bonds appear at what wavenumbers

A

2100-2300

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7
Q

the left side of the spectrum contains signals produced from what bonds

A

X-H bonds (eg C-H, O-H)

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8
Q

bonds that have a stronger dipole moment will produce what kind of signal

A

higher intensity signal than weaker dipole moment

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9
Q

if a compound is symmetrical what signal is produced

A

no signal

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10
Q

what does the location of each signal indicate in NMR

A

number of different kinds/electronic environments protons are in

environment of protons that give rise to signals

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11
Q

what does the area under each signal indicate in NMR

A

number of protons giving rise to the signal

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12
Q

what does the shape of each signal indicate in NMR

A

number of neighboring protons

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13
Q

protons in the same environment are

A

chemically equivalent

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14
Q

two protons will be chemically equivalent if they can be what

A

interchanged by rotation oe reflection

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15
Q

two protons will be chemically equivalent if they can be what

A

interchanged by rotation or reflection

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16
Q

how many signals will show up for the 3 protons of a CH3 group

A

one signal

chemically equivalent

17
Q

if there are no chiral carbons will the 2 protons of the CH2 group be chemically equivalent

A

yes

18
Q

if there are chiral carbons will the 2 protons of the CH2 group be chemically equivalent

A

no produces separate signals

19
Q

if 2 CH2 groups can be interchanged by reflection or rotation are they equivalent

A

yes produces one signal

20
Q

what is the chemical shift

A

relative to freq of absorption of reference compound TMS

21
Q

what is intergration

A

area under each signal

22
Q

what is multiplicity

A

number of peaks in each signal

23
Q

if n is the number of neighboring protons then what will be the equation to find the multiplicity

A

n + 1

24
Q

what is considered neighboring protons

A

if 2 or 3 sigma bonds separate them