Week5-C1 Flashcards

1
Q

What is the common factor between all lipids?

A

Their insolubility in water.

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2
Q

What are the 3 types of lipids found in food and in the human body?

A

1-triglycerides
2-phosopholipids
3-sterols

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3
Q

The ____ are the most abbondant type of lipids found in the food, and most specifically the ___

A

Glycerides category

triglycerides

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4
Q

Complete : The _____ group of a fatty acid will readily react with the ____ group of glycerol producing a lipid (MG, DG or TG) and one molecule of water

A

carboxyl

hydroxyl

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5
Q

The fatty acid chains ranges from ___ carbons to ___ carbons

A

4 to 28 carbons

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6
Q

When forming a triglycerides you need ___ molecules of H20

A

3

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7
Q

The oxygen from the ____ group of the ___and H from carboxyl group and from the hydroxyl group

A

carboxyl

FA

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8
Q

Glyceride are considerer to be polar or non-polar?

A

it depends on the number of FA attached to the glycerol. If 3 are attaches, they are non-polar but if they have less then 3 attached they are partially polar because of the hydroxyl group of the glycerol (partially soluble)

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9
Q

Monounsaturated fatty acids have __ double bond and are found in ___, ___ (oil) and in ___ and ___ (nuts)

A

one

olive and canola oils, almonds, and walnuts

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10
Q

Omega-3 (ω3) and omega-6 (ω6) fatty acids are ___

fatty acids.

A

polyunsaturated

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11
Q

ω3 and ω6 designate the position of the 1st double bond when the
fatty acid chain is numbered from the ____ end.

A

methyl

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12
Q

What are the two geometric isomers? what is the most common one?

A

cis and trans and cis is the most common one

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13
Q

What is the major fatty acid in olive oil?

A

Oleic acid (cis-monounsaturated).

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14
Q

What is the trans isomer of the major FA in olive oil?

A

Elaidic acid

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15
Q

How do you characterize the fatty acids? (technique)

A

Fats and oils are often characterized by hydrolyzing all the ester
bonds with a strong base (to liberate the fatty acids from the glycerol
backbone) and then analyzing the composition of the resulting mixture
of fatty acids.

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16
Q

What commodity doesn’t contain a free fatty acid content below 1%?

A

Olive oil

17
Q

What is the most important physical property of FA?

A

the melting temperature.

18
Q

The melting point of FA :

  1. Increase with ____ chain length
  2. Decreases with ____ number of cis doubles bonds
  3. _____ with isomerization of cis to trans
A

increase
increase
increase

19
Q

Why does most of plant based oil are liquid at room temperature?

A

because they contain a lot of unsaturated fatty acids in the cis configuration

20
Q

What manipulation can you do to FA to increase the solidity at room temperature

A

You can saturate the FA (catalytic hydrogenation)

21
Q

True or False : The solidity at room temperautre decrease with the number of double bonds

A

true

22
Q

Complete : Lipids from plant sources tend to be more ____ and are ___.

A

unsaturated

oil

23
Q

Complete : Lipids from animal sources tend to be more ____ and are ___

A

saturated

fat

24
Q

Complete : lipids from fish sources tend to be ____ oils

A

highly polyunsaturated

25
Q

Complete : an increase in cis double bond ____ the melting point

A

decrease

26
Q

What happens when to the double bond when you subject fatty acids to catalytic hydrogenation

A

The double bond either disappear or change configuration from cis to trans.

27
Q

What is the alternative process to catalytic hydrogenation?

A

Interestierification

28
Q

What is interesterification?

A

A process by witch you change the positions of the FA on the glycerol, changing the properties.

29
Q

What are the advantages of the hydrogenation ? (3)

A
  1. Longer SL
  2. Greater stability and lower production cost
  3. Faster dissolving and setting propreties in chocolate production
30
Q

What is the name of the smallest fatty acid

A

Butyric acid.

31
Q

Why does tropical oils have a low melting point even thought they are saturated FA

A

Because they have a short chain length.