Weathering Processes and Sediments Flashcards
What is the geomorphic significance of phys and chem breakdown of surface materials?
- Easily manipulated materials that can form new landscapes and landforms
- Production of seds, sed landforms, by-products (cements), soils
- Linked to control of other geo processes (karst topo, mass wasting, colluviation, aeolian landforms, glacio/fluvial processes)
Why is weathering a disequilibrium response of rock bodies or sediment
- Conditions at the surface (or transport/deposition) are very different from those of rock formation
- ie. heat, pressure, chemistry, mechanical action
What are the 2 main processes of weathering?
- Chemical decomposition
- Physical disintegration
- both work simultaneously often
What are types of physical weathering?
- pressure release
- freeze-thaw
- thermal expansion
- salt crystal growth
- biotic
- hydration
What are types of chemical weathering?
- Solution
- Ion Exchange
- Hydrolysis
- Oxidation
Mechanical Weathering
- No change in chemical composition, just disintegration into smaller pieces
- Increases total surface area which makes it more vulnerable to further breakdown/weathering
Chemical Weathering
- Breakdown a a result of chemical reactions/ alterations
- Limestone or marble
Role of Phys/Mech Weathering
1) Reduces rock material to smaller fragments that are easier to transport
2) Increases exposed surface area making rock more vulnerable to further physical and them weathering
Pressure Release
- Uncovered rock expands due to lower confining pressure
- Results in Exfoliation
Exfoliation
- Igneous rocks formed at depth exfoliate at surface
- Rock breaks apart in layers that are parallel to the earth’s surface
- Creates slab-like morphology
- Slabs sheet off in onion-like layers
- Enhances weathering and erosion, risk in mines
Freeze-Thaw/ Frost Wedging
- Rock breakdown by expansion of ice in cracks and joints
- Water expands 9% when frozen, up to 20million kgm^-2 pressure
- Significant in periglacial and seasonal climates
What is freeze-thaw/frost-wedging controlled by?
- Moisture content
- Rate of temperature change
- Freeze-thaw cycles
- Rock type (porosity etc.)
- Structure (fractured/jointedness of rock)
Thermal Expansion
- Due to extreme range of temps that can shatter rocks
- Desert envrs
- Repeated swelling and shrinking of minerals with different expansion rates also shatters rocks
Salt Weathering
- Evaporation of salt brine
- Grain by grain eventually produces cracks in the surf zone
Tafoni
- Salt weathering that creates a honeycomb like effect in rock surface
- Locally common in Nanaimo group sandstones
Biotic Weathering
- Root splitting: At large scales seedlings sprouting in a crevice
- Plant roots exert physical pressure
Hydration and Swelling
- Hydration: Attachment (adsorption) of water molecules to crystalline structure of a rock
- Causes expansion and weakness
- Mineral example: Anhydrite plus water = Gypsum
- Not chemical b/c easily reversed, no chem change
Expansive Clays
- Bentonite
- Expand 2:1
- Absorb 140x mass of water exert up to 55000 kmm^-2 pressure
- Quick glaciomarine clays
Resistance to weathering
Rock strength, composition, structure
- The form/density of fractures is controlled by rock type
- Biota (sort of)
- Porosity/cementation %
- Grain size (fine = more resistance)
Driving force of phys weathering
1) ice crystallization requires water
2) salt crystallization requires water
3) Biota growth requires water
- Temperature
- Joints are pathway for water that enhance mech weathering
Rock characteristics that control phys/mech weathering
- Mineral compostion and solubility
- Surface Area and grain size (clay has large and therefore absorbs more water)
- Joints, faults = natural pathways
Definition of chem weathering/decomposition
- Transformation/ decompostion (chem alteration) of one mineral into another
- Direct effect of atm or bio produced chems
- Almost always with water
- Weakens structure at mineral level
- Produces soluble materials and insoluble sediments transported in leachate, groundwater and/or runoff
- Synthesis of new secondary minerals, clay, oxides, precipitates
Solution
Process by which rock is dissolved in water (carbonation of limestone)
- Bio activity in soils generates CO2
- Bicarbonate is dominant ion in surface runoff (rivers)
- When water becomes saturated, chemicals may precipitate out forming evaporite deposits
Ion Exchange
- Substitution of ions in sol’n for ions in minerals
- Surfaces of clay particles (unsatisfied elemental charges, exposed hydroxyl groups, isomorphous substitution common)
- Isomorphous substitution (replacement by similar sized ions i.e. Si for Al or Al for Mg, no alteration in form of mineral)
Hydrolysis
- H and O in water with rock form new substances
- Carbonation is essentially same reaction but w/ CO2 instead of H+
- Feldspar weathering to kaolinite
- Most common mechanism for clay formation
Oxidation
- O dissolved in water promotes oxidation of sulphides, ferrous oxides, native metals
- Often cause of red soils
- Olivine with water and O to Hematite and dissolved silica acid
What is the main driver of chemical weathering?
WATER
- Ionic and organic compounds dissolve in water = dissolution
- Hydration and Hydrolysis both require water
- Acid reactions require water
Does chem weathering enhance phys/mech weathering?
Yes, enhances opportunity for more phys/mech weathering
Which minerals are most resistant to weathering? Least resistant?
- Most = Late stage minerals (Bowen’s Reaction Series) that are more stable at surface conditions
- Least = First to form (Olivines, pyroxenes etc.)
- (first = fastest, last = slowest)
Why is sand so prevalent on Earth’s surface?
- Sand mostly consists of quartz
- Quartz is relatively stable at surface and resistant to weathering (quartz ridges tend to stick out)
Fracturing
- Disintegration caused by mech weathering exposing more surface area
- Reduces volume per grain
- Greater surface area = more places for chem action
What is the primary way that weathered bedrock is churned up to form soil?
Biota
Chemical weathering is strongest with?
Increased Precip and temp
Phys weathering is strongest with?
Decreased temp and moderate precip
What important by-products does mech and chem weathering produce?
- Soils
- Sediments
- Landforms, karst topo, tafoni
- Secondary minerals, clays