Karst and Karst Terranes Flashcards
The word Karst stems from?
- German form of the Yugoslavian term “Kras”
- Meaning ‘bare stony ground’
In modern geomorphology, Karst refers to what?
- Landscape formed by dissolution of the underlying bedrock
- Characterized by distinctive landforms that don’t typically occur in any other circumstance
The term ‘pseudo-karst’ refers to?
- Karst-like development in non-carbonate lithology
- Exhibits characteristics similar to karst landscapes
- But lack dissolution as a primary means of landscape formation
Major known global karst regions
- Mexico, Mid US,
Canadian Rockies, SE Asia, Parts of Australia, Spain, Italy, etc. - Equatorial areas from high temps and are areas of both limestone formation and dissolution
- Exception is SA, not much there
BC carbonates
- Rockies
- Some on Van Isle and Haida Gwaii
Factors that affect Karst development
- Solubility of limestone (percent calcite)
- Climate (temp and moisture)
- Structure of limestone (joints, fractures, porosity)
- Mineralogy/Lithological content (percent classics, percent spar vs. micrite vs. skeletal)
- Vegetation/non-carbonate geology (acidity/pH of groundwater from humic acids)
- Atmospheric CO2 (affects solubility of carbonates)
What is the main thing karst topography requires?
- Limestone!
Overview of karst formation
- CO2 in air and soil combine w/ water to form carbonic acid, dissolves limestone, especially along fractures
- Subsurface dissolution/erosion forms water-filled caves
- Water table lowering drains caves, carbonates precipitate
- Cave roofs collapse, cause sinkholes/ other landforms
- Over time, erosion and dissolution lead to remnant rock towers (Asia)
Carbonate geochemistry
Rainfall is acidic (pH 5.6) b/c atmospheric CO2 and water produce carbonic acid
- Carbonic acid dissociates into hydrogen and bicarbonate ions
- Equilibrium equation
- Carbonic acid dissolves limestone to produce calcium and bicarbonate ions
Other controls on groundwater acidity and carbonate geochemistry
- Soil water gets highly enriched in CO2 from respiration of plant roots and microbe decomposition of organic matter
- Cold water can dissolve/hold more CO2 than warm
- More CO2 is dissolved in water as the partial pressure of the air increases (e.g. in soil pore space,), increases CO2 in oceans
- More limestone increases bicarbonate
What temperature of water can hold more CO2?
Cold water
Dissolution of carbonates
- Process by which rock is dissolved in water (assisted by carbonic acid)
What does increased CO2 in water do?
- Decreases pH
- Increases rate of dissolution
What does increased biological activity do?
- Enhances dissolution b/c it generates CO2
- CO2 generated by respiration of plant roots and decomposition of organic matter by microbes
What is the dominant ion in runoff?
- Bicarbonate, HCO3-
- Due to carbonate dissolution
Precipitation of carbonate is what?
- Opposite to dissolution
- Occurs when CO2 evaporates from water, e.g. in caves
Dissolution of Dolomite
- CaMg(CO3)2 breaks down to Ca2+, Mg2+, and 2C032-
- Rate of dissolution is higher if carbonic acid is involved, just like limestone
What are examples of other minerals that can dissolve in water?
- Dolomite, chalk, gypsum
- Break down into constituent ions
Karst landscapes are shaped through…?
- Dissolution of soluble bedrock
- Commonly limestone or dolomite
- Sinkholes develop and cavities are dissolved below ground
- Surface water may become limited
3 Cycles of karst terrain erosion
- Youthful (Normal surface drainage, to dry valley’s, swallow holes, underground streams)
- Mature (Roof collapse, surface hollows)
- Old age (Hums, and remnant rock towers, worn down to impermeable basement in areas)
Landforms that form above the water table
- Collapse sinkholes, karren, grikes, abandoned caves, speleothems
Grikes
- Kluftkarren
- Solution enhanced vertical fractures
- Divide surface into distinct pieces referred to as Clints
Speleothems
- Cave deposits
Landforms that form below the water table
- interconnected caves, tunnels, other cavities, solution sink-holes, springs
Karrens
- Large tracts of limestone karst terranes that are devoid of unconsolidated material
- Often solution enhanced vertical fracture/ joint sets
- Can be filled w/ debris from dissolution or devoid of residuum
- Not good for growing, sometimes loess may provide nutrients for plants to grow in cracks
- Openings known as grikes, kluftkarren or solution grooves
Ireland
- Karren, grikes and clints
- Limestone pavements, rugged and bare w/ flat areas of rock
- The Burren in county Clare formed during carboniferous (355-290Ma)