Water vapour, evaporation and precipitation Flashcards

1
Q

The rate oof change of pressure, P, with elevation or altitude z is given by

A

dP/dz = -ρg

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2
Q

what is the equation for density of dry air

A

ρda = P/RdaT

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3
Q

what is Rda

A

287 J/kg/K

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4
Q

What is the average near surface rate of decrease of temperature with altitude

A

dT/dz = -6.5 C°/km

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5
Q

what is the density of air at sea-level pressure, and density of dry air

A

Pa = 101.3kPa
ρda = 352/T

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6
Q

what is the equation for the density of water vapour

A

ρv = e/RvT

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7
Q

What is Rv equal to

A

461 J/kg/K

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8
Q

define atmospheric pressure

A

the sum of the partial pressures of the gases in the atmosphere
P = Pda + e

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9
Q

define vapor pressure

A

the partial pressure of water vapour, e

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10
Q

Is the mass of water greater or less than the mass of dry air

A

Mass of H2O is less than the mass of dry air

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11
Q

moist air can be treated as a mixture of

A

dry air an water vapour
ρma = ρda + e

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12
Q

Equation to find the molecular weight of moist air

A

Mma = e/ρma MH2O + ρda/ρma Mda

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13
Q

is the density of moist air greater than or less than the density of dry air

A

density of moist air is less than the density of dry air
ρma < ρda

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14
Q

what is the equation for the density of moist air

A

ρma = P/RdaT (1 - 0.378 e/P)

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15
Q

What are the 6 ways to quantify water vapor

A

vapor pressure
absolute humidity
specific humidity
relative humidify
Dew point
precipitable water

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16
Q

what is vapour pressure

A

the partial pressure of water vapour in the air

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17
Q

What is e*

A

saturation vapour pressure. It is the maximum vapor pressure that is thermodynamically stable. Also, the maximum amount of water vapor that the atmosphere can hold at that temperature.

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18
Q

e* is a function of

A

temperature

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19
Q

what is the equation for e* for a liquid, T > 0 C

A

e* = 611 e^(17.27T/(T + 237.3))

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20
Q

What is the equation for e* for ice, T < 0C

A

e* = 611 e^(21.87T/(T + 265.5))

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21
Q

If we are at e*, how can we get condensation to occur

A

lowering of the temp or adding more water vapor

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22
Q

describe absolute humidity

A

water vapor density
ρv
the mass of water vapour per unit volume of air

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23
Q

equation for the density of water vapor / absolute humidity

A

ρv = e/RvT

24
Q

describe the specific humidity

A

q = ρv/ρda = 0.622 e/P
ratio of water vapor density to the dry air density

25
describe relative humidity
ratio of the water vapor pressure to the saturation vapor pressure e*
26
describe dew point
The temperature to which a mass of air with a given vapor pressure has to be cooled in order to reach saturation point Tdp
27
describe precipitable water
If all the amount of water vapor in a column of the atmosphere of unit area extending from the surface to the top of the atmosphere is condensed into liquid water
28
Describe the 5 steps of the evaporation process
1. Assume that the vapor pressure equals the saturation vapor pressure at the surface temp (e*(Ts) = e(Ts)) 2. the water molecules at the surface are attracted to the ones under it. However, some have enough energy to break the hydrogen bonds and go above the surface. This escape energy increases as Ts increases 3. Some water mcl may re-enter the water. equilibrium of entry and exit is reached 4. water vapor in the air is at steady state, it cant increase anymore. ea (actual saturation) < e* because wind and temp prevents the air to be completely saturated. 5. evaporation rate ∝ (es* - ea) ( So if ea << es* the air has a high capacity to hold more water vapor and evaporation occurs faster.
29
Is the air dry or humid if ea is almost equal to es*
humid
30
Is the air dry or humid if ea is a lots less than es*
dry
31
If es* > ea we have
evaporation
32
is es* < ea we have
condensation
33
is es* = ea we have
nothing
34
What happens when humidity is 100%
Then we know es* = ea and then the evaporating water will sondense in the air to form fog or mist
35
The actual vapor pressure 𝑒𝑎 of water in the air at a given temperature 𝑇𝑎 reflects the amount of water vapor present. The saturation vapor pressure 𝑒∗(𝑇𝑎), on the other hand, represents the _________ vapor pressure the air can hold at that temperature before becoming __________.
maximum saturated
36
𝑒𝑎 can be less than or equal to 𝑒∗(𝑇𝑎) . This means the air can either be _________ (relative humidity <100%) or ______ _________ (𝑅𝐻=100%).
undersaturated fully saturated
37
Evaporation will occur even if the relative humidity equals 100%, as long as 𝑒s* ___ 𝑒a
>
38
Evaporation occurs in exactly the same way whether the underlying surface is ________ or _________. The only difference is that the saturation vapor pressure/evaporation for an ice surface at a given temperature is slightly _______
liquid water ice/snow lower
39
what are the 3 inferences we can make from the evaporation process
Inference #1: es* > ea we have evaporation, opposite is condensation Inference #2: When humidity = 100% we have fog and mist. evaporation happens as long as es* > ea Inference #3: Evaporation occurs in exactly the same way whether the underlying surface is liquid water or ice/snow. The only difference is that the saturation vapor pressure/evaporation for an ice surface at a given temperature is slightly lower
40
The latent heat of ____________ λv, is the quantity of heat energy that is absorbed to break the hydrogen bonds when __________ takes place. This same quantity is released when the bonds are reformed upon _____________
vaporization evaporation condensation
41
__________ is always accompanied by a transfer of heat out of the evaporating surface; i.e., the surface cools.
evaporation
42
_________ in the atmosphere is always accompanied by a transfer of heat into the air; i.e., the air warms.
condensation
43
__________ on the surface is always accompanied by transfer of heat to the surface; i.e., the surface warms.
condensation
44
what are the two cases for latent heat exchange
Case #1: The rate oof latent heat-transfer in evaporation at water surface Case #2: The rate of latent-heat transfer in sublimation at ice surface
45
What is the equation for the first case of latent heat exchange: The rate oof latent heat-transfer in evaporation at water surface
λE = λv ρw E
46
what is the equation for the second case of latent heat exchange: The rate of latent-heat transfer in sublimation at ice surface
λE = ( λf + λv) ρw E
47
What is the difference between the equation to find the rate of latent heat-transfer for evaporation vs sublimation
the evaporation only considers the latent heat of fusion λv The sublimation is the sum of the latent heat of vaporization and latent heat of fusion, λf + λv
48
Is the latent heat of fusion smaller or larger than the latent heat of vaporization
smaller
49
does λv and λf depend on temp
λf doesnt depend on Temp. whereas λv does
50
What are the 4 steps to the precipitation process
1. Cooling to the dew point 2. Condensation 3. Water droplet growth 4. Importation of water vapor
51
Describe the first step of the precipitation process
Cooling: Without condensation: air cools at the dry adiabatic lapse rate Γda = 1∘C/100 m With condensation: The release of latent heat reduces cooling to the saturated adiabatic lapse rate: Γs 0.5∘C/100 m weighted average: of the previous two Γ = 0.65∘C/100 m Rising air expands and density decreases as pressure decreases Uplift rates: 1m/s for frontal zones and 30 m/s for thunderstorm. The thunderstorm drives stronger colling and precipitation
52
describe the second step of the precipitation process
Condensation: When air above the freezing point is cooled to the dew-point, liquid water is thermodynamically stable and randomly colliding water-vapor molecules tend to form tiny water droplets.
53
_____________ releases latent heat, which tends to sustain the _____________ process by warming/heating the surrounding air, reducing its density (a), and increasing its tendency to rise, cool, and produce more ____________.
condensation precipitation condensation
54
For example, some 10^8 (100 million) molecules (H2O) must collect to form a stable water droplet of about _____ diameter.
10^–4 mm (0.1 microm)
55
Describe the third step of the precipitation process
Condensation clouds form when: 1. water vapor is present 2. there is sufficient degree of uplift to bring cooling to the dew point In order for precipitation to fall from clouds, droplets must grow in size such that: 1. falling velocities exceeds the rate of uplift 2. can survive evaporation as they fall The droplets grow in size by: 1. coalescence 2. The e* of ice < e* liquid. This difference allows water to evporate and condense into ice. So they ice grows at the expense of the liwuid water
56
describe the fourth step of the precipitation process
Importation of water vapour: shows that in order to generate significant amounts of precipitation, vapor-bearing winds must continuously provide water vapour to precipitation-producing clouds, which is called importation of water vapour.