Water and Solutions Flashcards
Define Latent Heat of Fusion
The energy required to convert one mole of a substance from a solid to a liquid at its melting point
Define Latent Heat of Vaporisation
The energy required to convert one mole of a substance from a liquid to a gas at its boiling point
Define Specific Heat Capacity
The energy required to raise the temperature of 1g of a substance by 1 degree Celsius
Define Density
A measure of the mass of a substance per unit volume (eg g/L)
Define Solubility
The degree to which a given solute will dissolve in a given solvent. Often expressed quantitatively with the units ‘g/100g solvent’
Dissolution
The process of dissolving. Called dissociation for ionic compounds (as the ions ‘dis-associate’)
Miscible
Refers to two liquids which can mix together readily (opposite = immiscible)
Solvation
The process of water molecules surrounding a solute molecule or ion and bonding with it
Ionisation
A reaction between a molecule (eg an acid) and water, resulting in the formation of two dissolved ions
Suspension
Where a solid substance is dispersed in a solvent but not dissolved. The solid particles are distinguishable from the solvent particles. Suspensions usually settle over time and the solid can be separated by filtration.
Colloid
A stable suspension, which will not settle over time
Ion-dipole force
An attractive force between an ion and the oppositely charged pole of a polar molecule (such as water)
Ionic Equation
A chemical equation in which the ‘spectator ions’ are omitted.
solute
A Substance being dissolved
%w/w
Concentration of a dissolved solute with the effective units of g/100g solvent
Solvent
Liquid that dissolves a substance
Solution
Solvent and solute mixture
Solubility Curve
A graphical depiction of how the solute concentration required to form a saturated solution changes across a range of temperatures
Saturated Solution
A solution in which the maximum amount of solute is dissolved, at that temperature
Unsaturated Solution
A solution in which less than the maximum amount of solute is dissolved, at that temperature
Supersaturated Solution
A solution in which more than the maximum amount of solute is dissolved, at that temperature. This is an unstable situation which can arise when a saturated solution cools, and is likely to result in crystallisation of some of the solute
Strong Acid
Donate protons easily, Completely, ionise in solution
Weak Acid
Does not donate protons easily,
Partially ionise in solution
Formula to Calculate pH
pH = – log [H+]
Calculation to find [H+]
[H+] = 10-pH
Units are molL-1
pH scale range for acids and pH scale range for bases
1-6 & 8-14
Conjugate Acid
“Conjugate” acids are found on the products side of the equation.
A conjugate acid is the same as the starting base plus H+.
Conjugate Base
Conjugate bases are found on the products side of the equation.
A conjugate base is the same as the starting acid minus H+.