water and pores Flashcards
w/c ratio
0.36 ~ 0.42
w/c above 0.42
; excess capillary pores and water
w/c below 0.36
; unhydrated cement
theory of 0.36
; there is no extra water left beyond what is required for hydration and some cement unhydrated
theory of 0.42
; hydrate all the cement but with little water left
Higher w/c
; more capillary pores
capillary porosity
; amount is function of w/c and time
; not only porosity but also important for strength and permeability
; water has surface tension and movement like evaporation causes crack and shrinkage
Pros and cons of unreacted cement
+ unhydrated cement occurs when low w/c
+ less capillary voids
- expect autogenouse shrinkage
Hydration characteristics
; kinetics : how rapidly cement compounds react w/ water
; Fineness : how fineness controls the rate of reaction
; Heat : how much heat is produced , exothermic process
C-S-H
; Calcium Silicate Hydrate
; Core compound of strength imparting
; Chem. composition varies
; Main heat producer
C-H
; Calcium hydroxide
; Not strength imparting compound
; Vulnerable to sulfate
; Water soluble
; hexagonal crystalized material
Micro pores
; in btw C-S-H particles, size of pore is big enough for water to access, vulnerable to freeze -thaw
; surface tension is not large
; chem. reaction with final products occurs
Capillary pores
; Excess of the water
; surface tension is low, lager pores, affect permeability
; surface tension is high, smaller pores, affect deformation and cracks due to contraction of pores
Inter layer pores
; C-S-H particle has pores with water entrapped
; Surface tension is high and not affect permeability (or shrinkage) , hard to remove water