Admixture Flashcards
Admixture
; an ingredient other than water, agg.,hydraulic cement and fiber reinforcement
:it is added to batch immediately before or during mixing
Mineral Admixtures
; Fly ash (C,F) - by products of coal ; Silica fume ; Meta kaolin ; slag ; calcined shale
superplasticizer (chem admix)
; Break electro charged inter particle attraction ( should check again)
cementitious activity (with water)
; hydraulic cement reaction (with water)
main reasons of using SCM
economic
environmental
work ability
durability
OPC»_space; SLG»_space; Flyash (C(not calcium but memorize), high lime)»_space; Flyash(F, low lime)»_space; Slicafume
high cementitious (calcium + silica)»_space;> Highly pozzolanic (lower calcium + higher silica)
Lengthens set time of fly as on concrete
; it means less heat and strength development
depends on situation. it’s not always beneficial. what if cold weather
Flyash
; commonly used to reduce heat
; non combustible residue of powdered coal react with react with CH to produce CSH
; slower reaction rate -> strength develops slowly
improve durability by reducing permeability
Limitation of high content of silica-fume
; only little calcium hydroxide is going to react
Size of silica fume grains and workability
; Large surface area (small particles) = randomly charged this tiny particles have even stronger attractions btw inter particle
; To break out the interconnection, Need admixtures (superplasticizer)
Benefits of Silicafume
\+ Superpozzolanic (reactivity, high strength) \+ Shape of particles (round, workable) \+ densify (small size, particle packing) \+ high chemical resistance \+ low permeability
pozzolanic reaction (or activity)
; extra silica takes/ reacts calcium hydroxide that has been produced by hydration btw cement and water
;and produces more C-S-H (helps strength, reducing permeability, durability)
; reaction rate is affected
calcium hydroxide could make salt and create voids in the system.
why is extra silica important
; ??? because of pozzolanic reaction
Higher content of C-S-H and lower content of CH
+ stronger b/c less porous
+ less porous means more durable
+ more resistant to leaching b/c more C-H contents ???
+ more durable
benefits of shape of fly ash(FA)
+ FA is spherical so better workability, better packing efficiency, reduced voids
+ Gained workability provides a chance to use less water so less porosity, less permeability, and better durability