Admixture Flashcards
(29 cards)
Admixture
; an ingredient other than water, agg.,hydraulic cement and fiber reinforcement
:it is added to batch immediately before or during mixing
Mineral Admixtures
; Fly ash (C,F) - by products of coal ; Silica fume ; Meta kaolin ; slag ; calcined shale
superplasticizer (chem admix)
; Break electro charged inter particle attraction ( should check again)
cementitious activity (with water)
; hydraulic cement reaction (with water)
main reasons of using SCM
economic
environmental
work ability
durability
OPC»_space; SLG»_space; Flyash (C(not calcium but memorize), high lime)»_space; Flyash(F, low lime)»_space; Slicafume
high cementitious (calcium + silica)»_space;> Highly pozzolanic (lower calcium + higher silica)
Lengthens set time of fly as on concrete
; it means less heat and strength development
depends on situation. it’s not always beneficial. what if cold weather
Flyash
; commonly used to reduce heat
; non combustible residue of powdered coal react with react with CH to produce CSH
; slower reaction rate -> strength develops slowly
improve durability by reducing permeability
Limitation of high content of silica-fume
; only little calcium hydroxide is going to react
Size of silica fume grains and workability
; Large surface area (small particles) = randomly charged this tiny particles have even stronger attractions btw inter particle
; To break out the interconnection, Need admixtures (superplasticizer)
Benefits of Silicafume
\+ Superpozzolanic (reactivity, high strength) \+ Shape of particles (round, workable) \+ densify (small size, particle packing) \+ high chemical resistance \+ low permeability
pozzolanic reaction (or activity)
; extra silica takes/ reacts calcium hydroxide that has been produced by hydration btw cement and water
;and produces more C-S-H (helps strength, reducing permeability, durability)
; reaction rate is affected
calcium hydroxide could make salt and create voids in the system.
why is extra silica important
; ??? because of pozzolanic reaction
Higher content of C-S-H and lower content of CH
+ stronger b/c less porous
+ less porous means more durable
+ more resistant to leaching b/c more C-H contents ???
+ more durable
benefits of shape of fly ash(FA)
+ FA is spherical so better workability, better packing efficiency, reduced voids
+ Gained workability provides a chance to use less water so less porosity, less permeability, and better durability
fly ash, slower reaction rate
; react with CH and produce additional C-S-H
; slower the strength gain rate
; slower development of strength
+ improve durability by reducing permeability
silica fume
; byproduct of the silicon metal, very small grains
; high silica content (95%)
; super pozzolan
why we can get rid of fly ash and make full of silica fumes in mixtures
; maximizing reaction in the system is limited to calcium hydroxide reaction, silica fume react instead
Ca(OH)2 = CH
; if concrete is exposed to water, calcium hydroxide could make salt and create void
effects of fly ash in set time
+ lengthening set time can control a heat in hot weather conditions.
; Reduce early age strength but higher strength in long term age
- In cold weather, not helping
Air Entraining Agents
; Introduce air bubbles on purpose
; voids are not inter connected = not increasing permeability
; entrained air helps reducing freeze and thaw cycles
Air Entraining Agents
; Introduce air bubbles on purpose( void spacing, size, and amount), causing water to foam and to produce spherical air bubbles in the cement paste
; voids are not inter connected = not increasing permeability
+ entrained air helps reducing freeze and thaw cycles, acting as pressure release vessels because bubbles are well distributed
; air bubbles are not visible
Entrapped Air
- entrapped air is created during improper mixing, consolidating and placement
effects of entrained airs
+ slightly improve workability because bubbles reduce internal friction, acting like fine elastic agg.)
+ lower segregation and bleeding b/c improving workability
+ improve cohesiveness
+ reduce freeze-thaw
- reduce strength