Water Activity Flashcards
Water Content
How many g water is present in 100g in food and drink
Water activity
Water that is not strongly bound to other molecules
Determines food properties
Properties of water
Polar
Adhesion and cohesion
Binds to hydrophilic molecules
Causes phase seperation
Adhesion and cohesion
Surface tension
Capillary tube action - means hard to remove water from pores as acts against gravity
Phase seperation
Hydrophobic molecules are separated from water and squeezed out
Water activity
Amount of water available to form new hydrogen bonds
Pure water has an aw of 1.0
No available water is 0.0
Drying
Removing water lowering the water activity
Freezing
Reduces water that is available as frozen crystals are not available to form hydrogen bonds
Spoilage and water activity
Growth of microorganism
Only occur above certain water activity
Vapour Pressure
At any temperature there will be some molecules that have vaporised.
Water leaves water pool enter vacuum
H2O in vacuum enters water pool
Equilibrium does reach
Vapour pressure and solutes
Dissolved molecules reduce vapour pressure
Proportional to number of dissolved molecules
Not relevant to size
Hence why large molecules do not affect water as much as small in same concentration
Vapour pressure and salt reduction
Relevant to food as reduction of salt increases water activity
Vapour pressure and water activity
Relative vapour pressure = Vapour pressure / Vapour pressure pure water = Water activity
Chemical and enzymic reactions related to RVP
Relative humidity %
Relative Vapour Pressure x 100
Properties of Ice
Ice is lighter than water as H2O molecules not random so less packed