Volumetric analysis Flashcards
Is a quantitative analysis based on the measurement of the volume of solution that gives reaction.
Volumetric analysis
The concentration of the analyte can be found by reacting it with
A standard solution with a known concentration
The volumetric analysis is based on the
stoichiometry between reactive species
The reason for dilution _________ or that analysis can be repeated when necessary.
Dilution ratio:
Dilution factor:
Reduction of reagent or increase of volume of samples
amount before
amount after
Are solutions that have exactly known concentration and react with analytes
Standard solution
The standard solution
can be prepared by _______
Then,the precise concentration of the standard solution can be found by ________
Precisely weighing the required amount of reagent.
The reaction with special substances called primary standards
A _______ is highly pure compound that serves as a reference material in volumetric and mass titrimetric methods. The accuracy of a method is critically dependent on the properties of this compound.
primary standard
Requirements for a primary standard
- Highly pureorexactpuritymustbeknown.
- Atmosphericstability.
- Absenceofhydratewatersothatthecompositionofthesoliddoesnotchangewithvarioushumidity.
- Modestcost.
- Reasonablesolubilityinthetitrationmedium.
- Reasonablylargemolarmasssothattherelativeerrorassociatedwithweighingthestandardis minimized.
Characteristics of Quantitative Reaction
- Reaction must be specific and unique.
- Reaction must be in one direction.
- There action must be fast.
- The end of the reaction Can be detected easily.
- The reaction must be repeatable yieldings a meresultseverytime.
Characteristics of Quantitative Reaction
- Reaction must be specific and unique.
- Reaction must be in one direction.
- There action must be fast.
- The end of the reaction Can be detected easily.
- The reaction must be repeatable yieldings a meresultseverytime.
Primary standards for acid standardization
Primary standards for base standardization
KHCO3 Potassium bicarbonate TlCO3 Titanium carbonate Na2CO3 Sodium carbonate ....... KHC8H4O4 Potasium phtalate H2C2O4. 2H2O oxalic aid HC7H5O2 Hydrogen Benzoate