Complexometry Flashcards

1
Q

Is the association of two or more chemical species that are capable of independent existence by
sharing one or morepairsofelectrons

A

Complexation

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2
Q

It has found a wide application

since the discovery of organic derivatives,in most cases those of a-amino acids,______

A

complexones.

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3
Q

______ are stable complexes formed from the reaction of complexones with metal ions.

A

Complexonates,

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4
Q

Is one of the complexonates most often used for analysis.

A

Ethylendiamintetraacetate(EDTA)

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5
Q

In order to push the equilibrium of complexonate formation to the right,substances bindingH+ions, such as _________may beadded to thesolution.

A

ammonia buffer(NH4OH+NH4Cl),

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6
Q

iscausedbydissolvedcalciumandmagnesiumsalts.ItisexpressedbymillimolesofCa2+andMg2+ionsinaliter(mmol/l).

A

Water hardness

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7
Q

Caused by calcium and magnesium carbonates

A

Temporary hardness

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8
Q

Maintained by sulfates, chlorides, silicates, phosphates and nitrates of calcium and magnesium

A

Permanent hardness

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9
Q

theeliminationofcalciumandmagnesiumsaltsfromwater

A

Water Softening

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10
Q

Water is boiled until it evaporates and condenses, leaving behind impurities.

A
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11
Q

Water is boiled until it evaporates and condenses, leaving behind impurities.

A
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12
Q

Water is boiled until it evaporates and condenses, leaving behind impuritie

Boiling can be used to remove temporary hardness

A

Distillation

Physical Methods

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13
Q

Softening by
slakedlime, soda,sodium phosphate Na3PO4, sodium tetraborate Na2B4O7,or other materials,which forminsolublecarbonates,phosphates,boratesofcalciumorhydroxidewithmagnesiumsalts

A

Chemical methods

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14
Q

Employed on an industrial scale; makes used of natural or synthetic macromolecular compounds, called ion exchangers or ionites

A

Ion exchange

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15
Q

Ionites whose OH- ions neutralize the H+ ions form from the cationic proces

A

Anionites

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16
Q

Ionites exchanging their cations with those from water.

A

Cationites

17
Q

As ______ it is possible to use natural and synthetic aluminosilicates, which are called ____Na2[Al2Si2O8] · nH2O; thegeneralformulaNa2R). TheyadsorbCa2+, Mg2+ionsfromwa t e r,releasingNa+

A

Sodium cationites

Permutites

18
Q

As ______ it is possible to use natural and synthetic aluminosilicates, which are called ____Na2[Al2Si2O8] · nH2O; thegeneralformulaNa2R). TheyadsorbCa2+, Mg2+ionsfromwa t e r,releasingNa+

A

Sodium cationites

Permutites

19
Q

aresyntheticresins,whosehydrogencanbeexchangedbyionsofanymetals:

A

Hydrogen cationites

20
Q

Acids,whichareformed,gotothesolution. WhensuchwaterisrunthroughOH-anionites(simplifiedformulaROH),OH- ionsoftheanionitesneutralizehydrogenionsoftheacids. Therefore,runningwaterthroughthesystemofcationitesandanionitesallowstogetchemicallypurewater

A
21
Q

It is possibleto regenerate ionites:

A

Sodium cationites - NaCl
Hydrogen Cationites - H2SO4
Anionites- alkali solutions