VOCs Flashcards
What test is used for emission of VOCs?
Oddy test: accelerated ageing test.
What is the procedure followed in the Oddy test?
- Material enclosed in sealed glass boiling tube.
What materials were used in the Oddy test, and what dimensions?
- Pb
- Cu
- Ag
- Analar (99.5% pure or better)
Dimensions: 10x15x0.1 mm
Give one way (1) the corrosion of the metal coupons is accelerated.
- Ratio of material to airspace higher than expected in case or storage.
- concentration of Volatile corrosive gases higher.
Give one way (2) the corrosion of the metal coupons is accelerated.
- Metal coupon abraded to expose reactive metal surface.
- small hole pierced in coupon
- nylon monofilament threaded through hole and tied in place.
Give one way (3) the corrosion of the metal coupons is accelerated.
- Sample added to boiling test tube (a - 50 cm3), with seal.
- Tube (b - 0.5 cm3) filled with water, stoppered with cotton wool, added to boiling tube (a).
- Raises RH to 100%, accelerates corrosion.
Give one way (4) the corrosion of the metal coupons is accelerated.
- Temperature elevated to 60C
- Rate of emission increased
- Accelerates corrosion
Give one way (5) the corrosion of the metal coupons is accelerated.
- Control set up for each type of metal
- With metal coupon and water (NO test material)
Give one way (6) the corrosion of the metal coupons is accelerated.
- 28 days later test disassembled
What are the results obtained from the Oddy test?
Material classified as:
1. Suitable for permanent use (no corrosion)
2. For temporary use - max 6 months (slight)
3. Unsuitable (obvious)
What is the equation for the determination of the amount of sorbent recommended?
Q = (Co VN + ES) t / (PC1)
Q: quantity of sorbent
Co: Conc. outdoor pollutant (μg/m3)
V: Volume of air (m3)
N: AER (1/day)
S: exposed surface (m2)
T: minimum number of days pollutant maintained (days)
P: sorption capacity of sorbent (μg/g per μg/m3)
- Large P = better capacity for sorbent to trap pollutants
What are the units of P?
μg/g per μg/m3
What is the P value for acetic acid?
5.2
What is the P value for H2S?
7.5
What is the P value for NO2?
7.9