Vibrations and Rotations Flashcards

1
Q

what is the most simple approximation of a bond

A

a spring with a mass at each end

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2
Q

letter for frequency

A

v

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3
Q

what is mu in equation for frequency of vibration

A

reduced mass of the system

m1 x m2 / m1 + m2

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4
Q

equation for reduced mass of a system

A

m1 x m2 / m1 + m2

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5
Q

affect on reduced mass of a system equation when one mass is much bigger than the other one

A

m1 + m2 is basically the same as m1 if thats bigger so

m1 x m2 / m1 = m2 so only the mass of the smaller one matters

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6
Q

which particle vibrates when one is much larger than the other

A

only the smaller one oscillates

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7
Q

application of bond vibration theory

A

UV spectra

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8
Q

what force causes the curved trajectory of pendulum

A

tension of a wire

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9
Q

equation for downwards force on pendulum

A

Fw = mg

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10
Q

define simple harmonic motion

A

periodic motion under the effect a restoring force

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11
Q

what is the period of rotation

A

time for one revolution

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12
Q

define frequency

A

number of revolutions per second

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13
Q

what is the unit of frequency

A

Hz (s^-1)

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14
Q

equation for frequency

A

1/T

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15
Q

applications of theory of pendulum

A

orbit around the sun

orbit of electrons in an electronic or magnetic field or electrostatic force

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16
Q

what is tangential velocity on a curve

A

velocity at the edge of the disk

17
Q

equation for magnitude of velocity in constant rotation simple

A

v = 2piR / T
T is period of rotation
R is radius

18
Q

why use angular velocity equation

A

doesn’t use the radius so more general

19
Q

starting equations for average angular velocity

A
delta x / delta t
x is displacement between start and end
r delta theta / delta t
r is radius
theta angle of movement
20
Q

equation for angular velocity

A

delta theta / delta t

21
Q

what equation can the equation for angular velocity be substituted into

A

the second average velocity

one to get v = r w

22
Q

letter for angular velocity

A

w

23
Q

equation for kinetic energy

A

Ek = 1/2 m v^2

24
Q

equation for energy of a particle and how you got there

A

Ek = 1/2 m v^2 is equation for kinetic energy
then subtitute v with v = r w equation to get
Ek = 1/2 m r^2 w^2

25
Q

equation for moment of inertia around the axis of rotation

A

I = mr^2
substitute into Ek = 1/2 m r^2 w^2 to get
Ek = 1/2 I w^2

26
Q

what is rigid body rotation

A

two particles with a rigid bond rotating around a pivot point

27
Q

how to work out the total kinetic energy for both particles in a rigid bond

A

work it out individually and add them together where the two angular velocities can add wCl + wH = wHCl

28
Q

application of rotational theory

A

in rotational-vibrational spectra finding isotopic mixtures

29
Q

what is radius in a homonuclear atom

A

half the bond distance

30
Q

what is mass 1 equal to in a homonuclear atom

A

mass 2

31
Q

equation for moment of inertia around a point for homonuclear atoms H2

A

1/2 mH (dH2)^2