Unit B: Thermochemical Changes Module 4 Flashcards
Heat absorbed by water equation
Q=mcdeltat
Isolated System
energy and matter cannot move in or out
Calorimetry
process of measuring energy changes in an isolated system
Laws of Thermodynamics (x2)
- energy cannot be created or destroyed
- heat transfers naturally from warmer to cooler areas
Thermal Energy (Q)
represents the total kinetic energy of the entities of a substance
Specific Heat Capacity
amount of energy needed to raise the temp of 1 g of substance by 1 oC
Assumptions when using a calorimeter
- thermal energy gained by the container, lid , stirrer can be ignored/ are negligible
- calorimeters aren’t 100% efficient, some heat is always lost but its negligible
- aqueous solutions have the same density (1g/mL) and specific heat capacity as water
Moles equation
n= m (mass) / M (molar mass)
Calorimeter Inefficiency Equation (percent error)
experimental value -predicted value / predicted value x 100
Hess’s Law
if you combine the standard enthalpy change values of known reactions it will equal the standard enthalpy change of the final reaction (steps=final product)
Formation Reaction (deltafH)
1 mole compound is formed from its elements at standard conditions
Thermal Stability
tendency of a compound to resist decomposition when heated
if a compound takes more energy to decompose its more stable
Hess’s Law Predicting Enthalpy Equation
deltarH=molar enthalpy of formation of products - molar enthalpy of formation of reactants