Unit 4 Test Notes Flashcards

1
Q

What is a solute?

A

A substance that is dissolved in a solvent (ex. salt)

Solutes can be solids, liquids, or gases that are present in a smaller amount compared to the solvent.

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2
Q

What is a solvent?

A

The medium in which a solute is dissolved, often the liquid component of the solution (ex. water)

Solvents can be liquids, gases, or solids, but they are typically liquids.

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3
Q

Define a homogeneous mixture.

A

A uniform mixture of only one phase (looks the same throughout)

Examples include salt water and sugar water.

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4
Q

What is a solution?

A

A homogeneous mixture of substances composed of at least one solute and one solvent

It appears uniform throughout and does not separate upon standing.

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5
Q

What is a heterogeneous mixture?

A

A mixture where it is obvious that there is more than one substance present

Characteristics include being opaque, cloudy, and containing undissolved particles.

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6
Q

What is an electrolyte?

A

A compound that, in an aqueous solution, conducts electricity

Electrolytes are often ionic compounds that dissociate into ions when dissolved.

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7
Q

What is a nonelectrolyte solution?

A

A compound that, in an aqueous solution, does NOT conduct electricity

Nonelectrolytes are typically molecular compounds that do not dissociate into ions.

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8
Q

Fill in the blank: Acids form ______ solutions.

A

acidic

Acids increase the concentration of hydrogen ions (H+) in solution.

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9
Q

Fill in the blank: Bases form ______ solutions.

A

basic

Bases increase the concentration of hydroxide ions (OH-) in solution.

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10
Q

Fill in the blank: Water is known as the ______ solvent.

A

universal

Water’s ability to dissolve many substances is due to its polarity and ability to form hydrogen bonds.

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11
Q

What is dissociation in the context of ionic compounds in water?

A

The separation of individual ions from an ionic compound as it dissolves in water

For example, NaCl dissociates into Na+ and Cl- ions.

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12
Q

What does ‘like dissolves like’ refer to?

A

Polar substances dissolve in polar solvents; non-polar substances dissolve in non-polar solvents

This principle explains solubility behaviors based on molecular polarity.

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13
Q

What are hydrogen bonds?

A

A very strong intermolecular force formed when water is the solvent and solutes have N, O, or F lone pairs or H-N, H-O, or H-F bonds

Hydrogen bonding significantly affects the solubility of substances in water.

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14
Q

What is the role of London dispersion forces?

A

Weak intermolecular forces between non-polar substances that are responsible for dissolving non-polar solutes in non-polar solvents

These forces are significant in non-polar solute interactions.

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15
Q

True or False: Water is consumed during the dissociation of NaCl.

A

False

Water facilitates the dissociation process but remains unchanged in quantity.

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16
Q

What is the difference between a total ionic equation and a net ionic equation?

A

Total ionic equation includes all dissociated ions, while net ionic equation includes only reacting entities.

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17
Q

What is a total ionic equation?

A

A chemical equation in which all highly soluble ionic compounds are written as dissociated ions.

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18
Q

What criteria must a total ionic equation meet to be balanced?

A
  1. All entities on one side must be accounted for on the other side. 2. The net electrical charge must be the same on both sides.
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19
Q

Define spectator ions.

A

Ions that are not involved in a chemical reaction and do not react themselves.

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20
Q

True or False: Spectator ions participate in the reaction.

A

False.

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21
Q

What is a formula equation?

A

A chemical equation in which all compounds are represented by their chemical formulas.

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22
Q

What does the solubility table predict?

A

The solubilities of many compounds and whether an ionic compound will dissolve into ions or remain a solid.

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23
Q

Fill in the blank: The greater the number of _________, the more reactions occur.

A

collisions.

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24
Q

What happens when a solid dissolves into a solution?

A

It reduces into the smallest possible particles, creating a larger surface area and more collisions.

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25
Q

What is a net ionic equation?

A

A chemical equation that includes only the entities that react during the reaction.

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26
Q

List the types of equations discussed.

A
  • Formula Equation
  • Total Ionic Equation
  • Net Ionic Equation
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27
Q

What must you refer to when writing total and net ionic equations for reactions?

A

The solubility table.

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28
Q

Sample Problem: Write the total ionic equation and net ionic equation for the reaction of lead(II) nitrate and potassium iodide.

A

Refer to the solubility table for the specific equations.

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29
Q

Sample Problem: Write the net ionic equation for aluminum metal in copper(II) chloride solution.

A

Refer to the solubility table for the specific equation.

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30
Q

What is a saturated solution?

A

A solution that contains the maximum quantity of solute at a given temperature and pressure.

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31
Q

What defines an unsaturated solution?

A

A solution in which more solute can dissolve at a given temperature and pressure.

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32
Q

What characterizes a supersaturated solution?

A

A solution that contains more than the maximum quantity of solute that it should at a given temperature and pressure.

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33
Q

Define solubility.

A

The concentration of a saturated solution of a solute in a solvent at a specific temperature and pressure.

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34
Q

What are the common units for expressing solubility?

A

Grams per 100 mL of solvent.

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35
Q

What factors affect solubility?

A
  • Molecule size
  • Temperature
  • Pressure
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36
Q

How does temperature affect the solubility of solids?

A

Solids usually have a higher solubility in water at higher temperatures.

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37
Q

What happens to the solubility of gases as temperature increases?

A

The solubility of gases decreases.

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38
Q

What is a solubility curve?

A

A graph of the solubility of a given solute against temperature.

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39
Q

What do points on the solubility curve represent?

A

Saturated solutions.

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40
Q

What do points below the solubility curve represent?

A

Unsaturated solutions.

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41
Q

What do points above the solubility curve indicate?

A

Supersaturated solutions.

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42
Q

What is crystallization?

A

A process that occurs when some of the solvent evaporates out of a solution.

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43
Q

What characterizes high solubility?

A

A maximum concentration at SATP of greater than or equal to 0.1 mol/L.

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44
Q

Define low solubility.

A

A maximum concentration at SATP of less than 0.1 mol/L.

45
Q

What does it mean if a substance is insoluble?

A

It has negligible solubility at SATP.

46
Q

Fill in the blank: The concentration of a saturated solution must be accompanied by a _______.

A

temperature.

47
Q

True or False: Polar liquids generally decrease in solubility as temperature increases.

A

False.

48
Q

What happens to gas molecules as temperature increases?

A

They regain some energy and come out of solution.

49
Q

What is the definition of concentration?

A

The quantity of a given solute in a solution.

50
Q

What does a dilute solution refer to?

A

Having a relatively small quantity of solute per unit volume of solution.

51
Q

What does a concentrated solution refer to?

A

Having a relatively large quantity of solute per unit volume of solution.

52
Q

How is concentration calculated?

A

Concentration = Quantity of solute / Quantity of solution.

53
Q

What does ‘C’ represent in molar concentration?

A

Molar concentration (mol/L).

54
Q

What does ‘n’ represent in the formula for molar concentration?

A

The amount of solute in moles (mol).

55
Q

What does ‘V’ represent in the formula for molar concentration?

A

The volume of solution in litres (L).

56
Q

What is molar concentration?

A

The amount of solute, in moles, dissolved in one litre of solution.

57
Q

If n = 0.186 mol and V = 0.250 L, what is the molar concentration C?

A

C = 0.744 mol/L.

58
Q

True or False: Molar concentration can be expressed as M.

A

True.

59
Q

Fill in the blank: To calculate molar concentration when given mass, you must first convert to _______.

A

moles.

60
Q

What is the molar concentration of sodium carbonate if 5.00g is dissolved in 250 mL?

A

Calculation needed based on molar mass.

61
Q

What is the amount concentration of a solution containing 63 g of phosphoric acid in 250 mL?

A

Calculation needed based on molar mass.

62
Q

What pages should be read for further understanding of molar concentrations?

A

Pages 397-401.

63
Q

Where can you find practice questions related to molar concentration?

A

Questions on page 402 #3-7.

64
Q

What type of calculations are used to determine molar concentration?

A

Stoichiometric calculations.

65
Q

What is the formula for calculating concentration?

A

Concentration = Quantity of solute / Quantity of solution

66
Q

What does % v/v stand for?

A

% v/v means percentage volume by volume

67
Q

If vinegar is labeled as 5% acetic acid, how many mL of pure acetic acid are in 100 mL of vinegar solution?

A

5 mL

68
Q

What is the percentage by volume concentration of acetic acid in a solution containing 140 mL of acetic acid in a 500 mL bottle?

A

28% v/v

69
Q

What does W/V stand for in concentration measurements?

A

W/V stands for percentage weight by volume

70
Q

What does a 3% W/V concentration of hydrogen peroxide indicate?

A

3 g of hydrogen peroxide in every 100 mL of solution

71
Q

What is the percentage weight by weight concentration of silver in a sterling silver ring that has 11.1 g of pure silver and a total mass of 12.0 g?

A

92.5% w/w

72
Q

What units are commonly used for very low concentrations in environmental studies?

A

ppm, ppb, ppt

73
Q

What is 1 ppm equivalent to in terms of mass and volume?

A

1 g / 1000 L or 1 mg/L

74
Q

How do you calculate the concentration of oxygen in parts per million if 2.2 mg of oxygen is measured in 250 mL of water?

A

8.8 ppm

75
Q

What is the relationship between mass of solute and volume of solvent in a concentration calculation?

A

Concentration = mass of solute / Volume of solvent

76
Q

Fill in the blank: A box of apple juice has a fructose concentration of 12 g/100 mL, which is expressed as _______.

A

12% W/V

77
Q

What mass of fructose is present in a 175 mL glass of juice if the concentration is 12 g/100 mL?

A

21 g

78
Q

True or False: ppm can be expressed as 8.8 mg/L.

A

True

79
Q

What is the general formula for calculating the mass of solute when the concentration and volume are known?

A

Mass of solute = (Concentration) x (Volume)

80
Q

What is a standard solution?

A

A solution for which a precise concentration is known

Standard solutions are often prepared in a volumetric flask for precision.

81
Q

Define dilution in the context of solutions.

A

The process of reducing the concentration of a solution by adding more solvent

Dilution is commonly used in laboratory settings to achieve desired concentrations.

82
Q

What is a stock solution?

A

A solution that is in stock (available), usually a concentrated solution

Stock solutions are used as starting points for dilutions.

83
Q

What is the final concentration when 250 mL of a 16.0 mol/L nitric acid solution is diluted to 4.5 L?

A

Final concentration calculation needed

This question involves dilution calculations.

84
Q

If a 1.00-L bottle of acetic acid is labelled with a concentration of 17.4 mol/L and is diluted to prepare a 0.400 mol/L solution, what volume of diluted solution is prepared?

A

Volume of diluted solution calculation needed

This question requires understanding of dilution calculations.

85
Q

What was the concentration of the original test solution if a 10.00-mL sample is diluted to a final volume of 250.0 mL with a diluted concentration of 0.274 g/L?

A

Original concentration calculation needed

This problem demonstrates the reverse of a dilution calculation.

86
Q

What are the learning goals of this lesson on solutions and solubility?

A

Solve dilution calculation problems and explain the process of dilution

These goals guide the educational focus of the unit.

87
Q

Fill in the blank: A solution prepared in a _______ flask is known for its precision.

A

volumetric

Volumetric flasks are essential for preparing standard solutions accurately.

88
Q

What is the difference between quantitative analysis and qualitative analysis?

A

Quantitative analysis measures the quantity of a substance present, while qualitative analysis determines non-numerical information about a solution or reaction.

89
Q

What is qualitative analysis?

A

The determination of non-numerical information about a solution or reaction.

90
Q

Give an example of qualitative analysis.

A

Observing that a reaction is creating gas that is bubbling out of solution.

91
Q

What is quantitative analysis?

A

The measurement of the quantity of a substance present (e.g., stoichiometric calculations).

92
Q

How can quantitative analysis help chemical engineers?

A

It can help determine if an industrial chemical process is operating optimally.

93
Q

Why is quantitative analysis important in water quality analysis?

A

It is useful in determining if a contaminant is present in toxic amounts.

94
Q

Who can use quantitative analysis in medical labs?

A

Medical lab technicians can determine if a substance has a healthy or legal concentration in human blood.

95
Q

What is solution stoichiometry?

A

A method of calculating the concentration of substances in a chemical reaction by measuring the volumes of solutions that react completely.

96
Q

What conversion factor is used when studying solutions?

A

Molar concentration is used as a conversion factor, rather than molar mass.

97
Q

In Sample Problem #1, what is the mass of barium chromate that will precipitate?

A

5.94 g.

98
Q

What is the first step in solving Sample Problem #1?

A

Write a balanced chemical equation and state all givens.

99
Q

What is the formula for calculating the number of moles of potassium chromate in Sample Problem #1?

A

n = C × V.

100
Q

What is the mole ratio of K2CrO4 to BaCrO4 in Sample Problem #1?

A

1:1.

101
Q

What is the purpose of finding the limiting reactant?

A

To determine which reactant will run out first and limit the amount of product formed.

102
Q

What must you do to calculate the limiting reactant?

A

Determine the moles of each reactant and use the molar ratio.

103
Q

In Sample Problem #3, what is the first step to determine the mass of solid lead(II) sulfide formed?

A

Determine the amount of moles of each reactant.

104
Q

What is the balanced chemical equation for the reaction in Sample Problem #3?

A

Pb(CH3COO)2 (aq) + Na2S (aq) → PbS (s) + 2 NaCH3COO (aq).

105
Q

Fill in the blank: Solution stoichiometry is used to calculate the _______ of substances in a chemical reaction.

A

[concentration]

106
Q

True or False: Qualitative analysis provides numerical data about a reaction.

A

False.

107
Q

What is the molar mass of barium chromate used in Sample Problem #1?

A

253.33 g/mol.

108
Q

How do you determine the volume of Na2SO4 required in Sample Problem #2?

A

Use c = n/v after finding moles of BaCl2 and the mole ratio.