unit 4 states of matter solid liquid phase changes Flashcards

1
Q

Crystalline solid

A

Well ordered matter in a solid

Pattern within solid repeats itself

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2
Q

Amorphous solids

A

Do not have extensive ordering

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3
Q

Four types of crystalline solids

A
  1. Molecular
  2. Ionic
  3. Covalent
  4. Metallic
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4
Q

what are Molecular solids held together by?

A

Molecules held together by intermolecular forces

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5
Q

what are Covalent network solids? what are they held together by?

A

Extended structures of atoms held together by covalent bonds

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6
Q

what are Metallic solids? what are they held together by?

A

Metallic bonds

Cations in a sea of delocalized electrons

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7
Q

what are ionic solids held together by?

A

Held together by electrostatic attraction between a cation and anion

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8
Q

Liquids are molecular meaning

A

Intermolecular forces strong enough to keep particles close to one another but not strong enough to keep them from moving past one another

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9
Q

Surface tension

A

Amount of energy needed to expand a liquid

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10
Q

What causes surface tension

A

Intermolecular forces from down below

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11
Q

What are intermolecular forces like when surface tension occurs?

A

All directional

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12
Q

Cohesive forces

A

forces between molecules

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13
Q

Adhesive forces

A

forces between molecules and container

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14
Q

Sublimination

A

Solid to gas

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15
Q

Desposition

A

Gas to solid

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16
Q

What does breaking attractive drives require

A

Energy

17
Q

What does converse also holds mean? what do they require?

A

Forming bonds

Require release of energy

18
Q

For all substances what is the difference between vapour and fusion?

A

Enthalpy Vapour is always greater than the fusion phase

19
Q

Equation to find change in free energy

A

DeltaG=deltaH-TdeltaS

Change in free energy equals the change in enthalpy minus temperature multiplied by enthropy

20
Q

Change from heavy to lighter products what is the sign on entropy and enthalpy

A

Positive

21
Q

Change from lighter to heavier substance what is the sign enthalpy and enthropy

A

Negative

22
Q

Change in free energy signwhen the temperature is greater than 100K

A

Negative

23
Q

Change in free energy sign when the temperature is less than 100K

A

Positive

24
Q

Change in free energy sign with the temperature is equal to 100K

A

0

25
Q

Vapour pressure

A

The pressure of gas at equilibrium coexisting with a liquid or solid at a certain temperature

26
Q

what does vapor pressure depend on?

A

Vapour pressure depends on temperature

Strength of intermolecular forces

27
Q

Boiling point

A

Temperature what which vapour pressure of a liquid equals external pressure

28
Q

Normal boiling point

A

The boiling point at 1 atm