unit 4 states of matter solid liquid phase changes Flashcards
(28 cards)
Crystalline solid
Well ordered matter in a solid
Pattern within solid repeats itself
Amorphous solids
Do not have extensive ordering
Four types of crystalline solids
- Molecular
- Ionic
- Covalent
- Metallic
what are Molecular solids held together by?
Molecules held together by intermolecular forces
what are Covalent network solids? what are they held together by?
Extended structures of atoms held together by covalent bonds
what are Metallic solids? what are they held together by?
Metallic bonds
Cations in a sea of delocalized electrons
what are ionic solids held together by?
Held together by electrostatic attraction between a cation and anion
Liquids are molecular meaning
Intermolecular forces strong enough to keep particles close to one another but not strong enough to keep them from moving past one another
Surface tension
Amount of energy needed to expand a liquid
What causes surface tension
Intermolecular forces from down below
What are intermolecular forces like when surface tension occurs?
All directional
Cohesive forces
forces between molecules
Adhesive forces
forces between molecules and container
Sublimination
Solid to gas
Desposition
Gas to solid
What does breaking attractive drives require
Energy
What does converse also holds mean? what do they require?
Forming bonds
Require release of energy
For all substances what is the difference between vapour and fusion?
Enthalpy Vapour is always greater than the fusion phase
Equation to find change in free energy
DeltaG=deltaH-TdeltaS
Change in free energy equals the change in enthalpy minus temperature multiplied by enthropy
Change from heavy to lighter products what is the sign on entropy and enthalpy
Positive
Change from lighter to heavier substance what is the sign enthalpy and enthropy
Negative
Change in free energy signwhen the temperature is greater than 100K
Negative
Change in free energy sign when the temperature is less than 100K
Positive
Change in free energy sign with the temperature is equal to 100K
0