Unit 4: Solutions and Solubility Flashcards

1
Q

What is a real life example of Quantitive Analysis?

A

A breathalyzer; measures concentration of alcohol in exhaled air.

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2
Q

What is the formula for meauring concentration?

A

C= N/V

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3
Q

Dilute

A

A small quantity of solute per unit volume of solution.

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4
Q

Concentrated

A

A large quntity of solute per unit volume of solution.

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5
Q

How can the wrong concentration be fatal? What happens when it’s too low?

A

Red blood cells can swell and burst (hemoglobic crisis). Cells are deprived of nutrients and oxygen.

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6
Q

When a label indicates “V/V” what does this mean?

A

V/V indicated 2 liquids that are being mixed together.

The first V represents the solute dissolved in the solution.

The second V represents the final volume of the solution.

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7
Q

What is the equation for calculating a V/V percentage?

A

Csolution = vsolute/vsolution X100%

*Your answer should be in units % V/V*

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8
Q

When you use W/V instead of V/V?

A

When there is a mass involved in the question.

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9
Q

What is the equation for calculating a W/V percentage?

A

Csolution= m solute/vsolution X100%

*Your answer should be in units % W/V*

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10
Q

Molar Concentration

A

The concentration of a solution expressed as moles of solute per unit volume of solution. (mol/L)

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11
Q

Dilution

A

The process of decreasing the concentration of a solution by adding more solvent. This doesn’t change the quantity of solute, only it’s concentration.

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12
Q

What is the equation for finding the concentration of a diluted solution?

A

CiVi=CfVf

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13
Q

What are the 2 equations for finding ppm?

A

1) 1ppm= 1g / 1000L
2) 1ppm = 1mg/L

*Choose based on the units in your problem*

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14
Q

What was the Arrhenius Acid Theory?

A

Acids are compounds that contain hydrogen and can dissolve in water to release hydrogen into solution. The hydrogen gives up its electron to the other element in the solution.

Example: HCl

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15
Q

What was the Arrhenius Base Theory?

A

Substances that dissolve in water to release hydroxide ions into solution.

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16
Q

Neutralization

A

When a base an an acid are mixed together to produce water and a salt. The H (relesed by acids) and OH (released by bases) ions join to create the water.

17
Q

What are 2 properties of bases and 4 properties of their solutions?

A

Bases:

  • Water soluable
  • Electrolytes

Base Solutions:

  • Taste bitter
  • Slippery
  • Turn red litmus blue
  • Neutralize acidic solutions
18
Q

What are 2 properties of acids and 5 properties of their solutions?

A

Acids:

  • Water soluable
  • Electrolytes

Acid Solutions:

  • Taste sour
  • Not slippery
  • Turn blue litmus red
  • Neutralize basic solutions
  • React with active metal to produce hydorgen gas
19
Q

Strong Acids and Bases

A

An acid or base that dissociates completely into ions in water. They are also strong electrolytes.

Exmaples: HCl (acid) and NaOH (base)

20
Q

Weak Acids and Bases

A

An acid or base that dissociated or ionizes very slightly in water. They are also weak electolytes.

*Most acids and bases are weak*

Examples: CH3OOH (acid) and NH3 (base)

21
Q

Strong/Weak vs. Concentrated vs. Dilute

Why should we not confuse these terms?

A

Strong and Weak: How well the ions seperate

Concerntrated and Dilute: How watered down a solution is

It is possible to have a dilute solution of a strong acid or a concentrated solution of a weak acid.

22
Q

What factor determines the strength of an acid or base?

A

How well the ions seperate.

23
Q

What is Autoionization?

A

Sometimes the collisions between molecules transfer a hydrogen ion from one molecule to another. In pure water this rarely happens.

24
Q

What happens when water molecules gain and loose hydrogen?

A

Loose: OH-

Gain: H3O+

In neutral solutions the ratio of gaining and loosing hydrogen is equal*

25
What equation is used to determine the concentration/ PH of hydrogen ions when given the PH/Concentration?
(H+) = 10 -PH Example: (Determining Concentration) A solution has a PH of 6 and (H+) = 10 -6 mol/L 1 X 10-6 mol/ L OR (Determining PH) A solution has a concentration of 10-3 mol/L PH=3
26
What are the classifications on the PH scale?
PH less than 7= Acidic PH equal to 7= Neutral PH greater than 7= Basic (Alkaline)
27
What are the products when acids react with the following: a) Active Metals b) Carbonates c) Bases
a) Salt and Hydrogen Gas b) Salt, Carbon Dioxide Gas, and Water c) Salt and Water
28
Titration
The presice adddition of a solution in a buret into a measured volume of a sample solution.
29
Titrant
The solution in a buret during titration. The concentration of this solution is accurately know. It is called standard solution.
30
Sample
The solution being analized in a titration.
31
Acid-Base Indicator
Signals the end of the titration by sharply and permanently changing colour when the equivalence point is reached. Example: Phenolphthalein
32
Endpoint
A change is physical appearance that indicated a complete reaction.
33
Saturated Solution
A solution that cannot dissolve more solute.
34
Unsaturated Solution
A solution that could dissolve more solute.
35
Supersaturated Solution
A solution that contains more dissolved solute than a saturated solution at the same temperature.
36
What are the 3 ways temperature can affect solubility?
1) Solbility decreases with an increase in temperature 2) Molecules in a gas state have more kinetic energy than those in a iquid state 3) Heating a solution provides more energy to the gas molecules and they escape from the liquid (Ex: Flat Pop)
37
What are the 3 ways pressure affects solubility?
1) Pressure is the force per unit area 2) Pressure has a very little effect on the solubility of a liquid or solid but a signifcant difference on gas 3) The solubility of a gas in a liquid is proportional to the pressure of that gas above the liquid but is not affected by the pressure of any other gas
38
What are the factors that affect the rate of dissolving?
1) Temperature 2) Agittation or Mixing 3) Surface Area