Unit 4 Flashcards

1
Q

Solutions:

A

homogenous mixtures of two or more substances

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2
Q

Solvent

A

A compound of a solution that is present in the greatest amount

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3
Q

Solute

A

Any component in a solution other than the solvent (i.e, the other ingredients in the mixture)

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4
Q

How is a solution made?

A

By dissolving a solute in a solvent (solute is added to the solvent)

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5
Q

How are solutions described qualitatively?

A

As concentrated or dilute

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6
Q

Concentrated solutions…

A

have a large amount of solute compared to solvent

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7
Q

Dilute solutions…

A

have a small amount of solute compared to solvent

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8
Q

Saturated solution

A

a solution that contains the maximum concentration of a solute possible at a given temperature

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9
Q

Unsaturated solution

A
  • a solution that contains less than the maximum concentration of a solute possible at a given temperature
  • can dissolve more of the solute into the solution
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10
Q

Supersaturated solution:

A

a solution containing more than the maximum quantity of solute predicted to be soluble in a given volume of solution at a given temperature

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11
Q

Concentration units

PPM

A
  • grams of solute per million grams of solution
  • =grams of solute/grams of solution (all times 10^6)
  • OR mg of solute/kg of solution
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12
Q

PPB

A
  • grams of solute per billion grams of solution
  • ppb=grams of solute/grams of solution (all times 10^9)
  • OR micrograms of solute/kg of solution
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13
Q

How to find the amount of solute (moles or grams) in a given voume of solution?

A

Use molarity

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14
Q

Molarity formula

A

Molarity=# of moles of solute/# of L of solution

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15
Q

molarity formula rearranged

number of moles solute=?

A

(molarity)(# liters of solution)

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16
Q

Beer’s law

A

absorbance=molar absorptivity x path length x concentration of absorbing species

intensity of color can be used to measure concentrations

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17
Q

A (in Beer’s law)

A

absorbance (amount of light absorbed by sample)

18
Q

E (in beer’s law)

A

molar absorptivity

19
Q

b (in beer’s law)

A

path length

20
Q

c (in beer’s law)

A

concentration of absorbing species

21
Q

Stock solution

A

a concentrated solution of a substance used to prepare solution of lower concentration

22
Q

Dilution

A

the process of lowering the concentration of a solution by adding more solvent

23
Q

Ionic Theory of Solutions

A
  • proposed by Arrhenius to account for the electrical conductivity of water
  • proposed that certain substances produce freely moving ions when they dissolve in water, and these ions conduct electric current in an aqueous solution
24
Q

Electrolytes

A
  • An electrolye dissolves in water to give an electrically conducting solution
  • most ionic solids dissolve in water
  • ions in previously fixed states are free to move about, forming an electric current
25
Strong electrolyte properties
* Total dissociation * Efficient conductivity * Includes strong acids, strong bases, and soluble salts
26
Weak Electrolyte
* Partial dissociation * Slight conductivity * Weak acids and week bases
27
Nonelectrolyte
* no dissociation * n/a conductivity * includes molecular compounds
28
Ionic compounds in solution
* When an ionic compound is dissolved into solution, the molarity for each ion is based on how many ions there were in the salt * For example, in an aqueous solution that is 0.1M NaCl, your solution will have 0.1M Na+ ions and 0.1M Cl- ions based on the 1:1:1 mole ratio. * But if you have an aqueous solutio that is 0.1M Na2SO4, your solution will have 0.2M Na+ ions and 0.1M SO4 ions based on the 1:2:1 mole ratio.
29
H+ ions strongly associated with water molecules form...
Hydronium ions (H30+)
30
Acids
proton (H+ donors)
31
Bases
Proton acceptors
32
Neutralization
reaction that takes place when an acid reacts with a base a produces a solution of a salt in water
33
Salt
* product of a neutralization reaction * made up of the cation of the base plus the anion of the acid
34
amphiprotic
acts as acid or base (ex. water)
35
Titration
an analytical method to determine the concentration of a solute in a sample by reacting it with a standard solution
36
Standard solution
a solution of known concentration (also called the titrant)
37
Equivalence point
point when moles of added titrant is stoichiomerically equivalent to moles of substance being analyzed
38
End point
point reached when the indicator changes color
39
Precipitation
combining an insoluable cation with an insoluable anion forms a precipitate
40
Oxidation
loss of electrons
41
reduction
gain of electrons
42
Redox reactions
transfer of electrons