unit 3 - periodic properties Flashcards

1
Q

wavelength

A

distance between two peaks or troughs in a wave

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1
Q

waves

A

oscillation of a property over time or space; can transport energy from one point to another

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2
Q

frequency

A

number of wave cycles that pass a specified point in space per unit time

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3
Q

photoelectric effect

A

when light shines on a metal, electrons are ejected from the surface of the metal

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4
Q

photon

A

particle of light

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5
Q

line spectra

A

electromagnetic radiation emitted at discrete wavelengths by a specific atom in the excited state

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6
Q

Bohr model

A

each electron moves around the nucleus in circular orbits, each with a specific radius

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7
Q

heisenberg uncertainty principle

A

rule stating that it is impossible to determine both the momentum and position of a particle at the same time;
the uncertainty principle is a consequence of quantum particles exhibiting wave-particle duality

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8
Q

quantum number n

A

determines the size of the orbital;
must be equal to or greater than 1

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9
Q

quantum number l

A

determines the shape of an orbital sublevel;
an s orbital is marked by l = 0;
must be any number from 0 - (n - 1)

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10
Q

quantum number ml

A

defines the orientation of the orbital in space
can be any number from -L to L

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11
Q

quantum number ms

A

spin number; determines the direction the electron spins
can be -1/2 or 1/2

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12
Q

degenerate orbitals

A

orbitals that have the same energy (n)

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13
Q

pauli exclusion principle

A

no two electrons will ever have the same four quantum numbers

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14
Q

electron configuration

A

listing that identifies the electron occupancy of an atom’s shells and subshells

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15
Q

ground state

A

state in which the electrons in an atom, ion or molecule have the lowest energy level possible

16
Q

excited state

A

state in which electrons have gained some energy and possess more energy than in the ground state

17
Q

periodic table

A

a chart where elements are sorted by their atomic number

18
Q

metals

A

element that is shiny, malleable and conducts heat and electricity

19
Q

metalloid

A

element that possesses some properties of metals and some properties of nonmetals

20
Q

nonmetals

A

element that appears dull and conducts heat and electricity poorly

21
Q

main groups

A

elements in groups 1-3 and 13-18

22
Q

transition metals

A

elements in groups 3-12

23
Q

inner transition metals

A

elements on the bottom rows of the periodic table;

24
Q

valence electrons

A

the outermost electrons of an atom

25
Q

hund’s rule

A

every orbital in a subshell is occupied with one electron before any orbitals can be doubly occupied. all electrons in singly occupied orbitals have the same spin number / ms

26
Q

E = hv = (hc/λ)

A

Energy of a photon / radiation, where
- λ is in m
- h = (6.626 x 10^-34)

27
Q

c = λv

A

speed of light relating to wavelength and frequency

28
Q

1/λ = k(1/nf^2 - 1/ni^2)

A

used to find wavelengths of light emitted by hydrogen atoms

29
Q

E = (-kZ^2) / n^2

A

energy of an orbit in a hydrogen atom

30
Q

hc/λ = k(1/nf^2 - 1/ni^2) = ^E

A

An alternative expression for energy absorbed/emitted upon moving orbits

31
Q

covalent radius

A

1/2 the distance between the nuclei of two identical atoms when they are joined by a covalent bond

32
Q

ionization energy

A

energy required to remove an electron from a gaseous atom or ion

33
Q

effective nuclear charge

A

charge that leads to the coulomb force exerted by the nucleus on an electron;
nuclear charge - shielding;
increases across a period, decreases down a group

34
Q

shielding

A

the probability of another electron being between the electron of interest and the nucleus