UNIT 3 - Fertilisers Flashcards

1
Q

what do plants do when they grow?

A

they extract nutrients from the soil via their roots

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2
Q

what happens to plants over time?

A

the level of nutrients that they contain decreases and the nutrients need to be replaced in order to grow healthy crops.

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3
Q

what elements are essential for healthy plant growth?

A

the elements nitrogen, potassium, and phosphorus (NPK)

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4
Q

what are the fertiliser compounds for nitrogen?

A

nitrates & ammonium salts

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5
Q

what are the fertiliser compounds for phosphorus?

A

phosphates

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6
Q

what are the fertiliser compounds for potassium?

A

potassium salts

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7
Q

what must the fertiliser compounds be and why?

A

they must be soluble in water so that they can be taken up by the plant roots into the plant

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8
Q

what does Δ stand for in the Haber process?

A

change in enthalpy

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9
Q

what is the Haber process?

A

the industrial production of ammonia from nitrogen and hydrogen using an iron catalyst

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10
Q

what is the word equation for the Haber process?

A

N₂ + 3H₂ <—> 2NH₃ ΔH = -92kJ

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11
Q

why can true equilibrium not be achieved in the Haber process?

A

because it is a true open system

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12
Q

what type of process is the Haber process?

A

a continuous process

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13
Q

what does the catalyst do in the Haber process?

A

it provides a fast reaction rate and reasonable yield at lower temperature

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14
Q

what is the rate of reaction like at low temperatures in the Haber process?

A

at low temperatures the forward rate of reaction is too slow to be economical

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15
Q

what is the rate of reaction like at high temperatures in the Haber process?

A

at higher temperatures the rate of reaction increases but favours the reverse reaction

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16
Q

what does high pressure favour in the Haber process?

A

it favours ammonia production but the required equipment is costly to build and maintain

17
Q

what must be reached in the Haber process?

A

compromises must be reached between the competing factors

18
Q

what does maximum yield require in the Haber process?

A

high pressure and low temperature

19
Q

how is the Haber process made cost-effective?

A

by using 200 atmospheres, 400°C and an IRON CATALYST, giving it a 15% yield

20
Q

how is a 98% yield achieved in the Haber process?

A

the ammonia produced is condensed and the unreacted gasses are recycled

21
Q

what are the starting materials in the Ostwalt process?

A

ammonia, oxygen and water

22
Q

what is manufactured in the Ostwalt process?

A

nitric acid

23
Q

how is a 98% yield achieved in the Ostwalt process?

A

by using a PLATINUM CATALYST

24
Q

how many tons of nitric acid are produced annually and for what purpose in the Ostwalt?

A

sixty million tons are produced for the manufacturing of explosives and fertilisers

25
Q

what temperature is the platinum catalyst in the Ostwalt process?

A

800°C

26
Q

what are ammonia and nitric acids?

A

important compounds used to produce soluble nitrogen containing salts

27
Q

how are fertilisers made?

A

by neutralisation reactions