Unit 3 - Chemistry In Society Flashcards

1
Q

Metallic bond definition

A

A metallic bond is the electrostatic force of attraction between positively charged ions and delocalised electrons.

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2
Q

Matallic bond properties

A

Metallic elements can conduct electricity in any state.

This is because they have delocslised electrons (free to move).

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3
Q

Thermosoftening plastic

A

Thermosoftening plastics will melt when heated, so they can be reshaped, reused and recycled.

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4
Q

Thermosetting plastics

A

Thermosetting plastics can be reshaped as they are made and then permanently set. They cannot be reshaped, reused or recycled.

(E.g. kettles, plugs)

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5
Q

What do all monomers units contain?

A

A carbon to carbon double bond.

Monomers are alkene based and are unsaturated molecules.

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6
Q

What are polymers?

A

Polymers are long chained molecules which are made by joining monomers together.

Polymers are examples of plastics.

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7
Q

How are polymers made?

A

Polymers are made when lots of single unit monomers join together.

The reaction is called addition polymerisation.

A lot of energy is needed. It is often carried out at high pressure with a catalyst.

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8
Q

Addition polymerisation definition

A

Addition polymerisation is a chemical reaction that involves making a polymer through an addition reaction.

The polymer is made from unsaturated monomers joining together in long chains.

(Polymers are made when lots of single unit monomers join together).

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9
Q

Monomer definition

A

A monomer is a small molecule that can be joined together to form a polymer.

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10
Q

Repeating unit

A

The repeating unit is the shortest repeating section of the polymer.

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11
Q

Radioactive decay

A

Radioactive decay is when unstable nuclei become stable by giving out alpha, beta or gamma radiation.

Heavier isotopes are more unstable and so are more likely to be radioactive.

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12
Q

What are unstable nuclei called?

A

Radioisotopes

To become stable radioisotope undergo radioactive decay.

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13
Q

Alpha radiation/ particles properties

A

It is a positively charged particle so is attracted to negative plate.

Can only travel a few cm and are easily stopped by a piece of paper.

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14
Q

Beta particles/ radiation properties

A

(Caused when a neutron breaks down.)

Beta particles are electrons given out by the nucleus of an atom - has a negative charge and is attracted to a positive plate.

Can travel about 1m in air but can be stopped by 5mm of aluminium.

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15
Q

Gamma rays/ radiation properties

A

They are electromagnetic waves so are not affected by any charged plates.

They can travel long distances and can be stopped by 25mm of lead.

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16
Q

What are alpha particles

A

Alpha particles consist of 2 protons and 2 neutrons and have a positive charge. (Charge = 2+)

It is the nucleus of a helium atom.

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17
Q

What are beta particles?

A

Beta particles are electrons ejected from the nucleus of an atom.

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18
Q

What are gamma rays

A

Gamma rays are electromagnetic waves emitted from within the nucleus of an atom.

19
Q

Half-life definition

A

Half-life is the time taken for the radioactivity of a substance to fall to half of it’s original value.

20
Q

Uses of radioisotopes

A

Medicine - sterilising equipment, cancer treatment, used as a tracer in diagnostics.

Industry - used in smoke alarms, to ensure the thickness of paper, detect leaks.

Used to date materials.

Isotopes used in medicine are usually beta or gamma as they have short half-lives so they don’t stay in the patient too long.

In Industry, they tend to have much longer half-lives.

21
Q

What is the half-life of an isotope effected by?

A

The half-life of an isotope is constant. It is unaffected by chemical or physical conditions.

22
Q

Importance of fertilisers

A

Fertilisers are used to provide plants with the essential elements for growth. They restore essential nutrients in the soil.

23
Q

Elements found in fertilisers

A

Nitrogen (N)

Phosphorus (P)

Potassium (K)

24
Q

Ammonia properties

A

Clear, colourless gas

Pungent smelling

Very soluble - makes an alkaline solution.

Ammonia solution + acid —> ammonium salt + water

25
Q

What is ammonia?

A

Ammonia is nitrogen hydride (NH3) which is used to make fertilisers.

26
Q

Ammomia reaction

A

Ammonia solution + acid –> ammonium salt + water

27
Q

What is produced in the haber process?

A

Ammonia (NH3)

28
Q

Haber process balanced equation

A

H2(g) + 3N2(g) 2NH3(g)

29
Q

Conditions used in the haber process

A

The haber process uses moderate temperatures.
- (too low then the reaction is too slow, too high then too fast and so a reverse reaction takes place)

High pressure

An iron catalyst is used

30
Q

Ostwald process

A

Product - nitric acid

Reactant - ammonia, oxygen and water

Catalyst - platinum

31
Q

Equations for the reactions of metals

A

Metal + oxygen –> metal oxide

Metal + water –> metal hydroxide + hydrogen

Metal + dilute acid –> salt + hydrogen

32
Q

What happens when metals combine

A

They form alloys.

33
Q

Redox reaction definition

A

A redox reaction is when an oxidation and reduction reaction take place at the same time.

34
Q

Oxidation definition

A

Oxidation - loss of electrons by a reactant

O - oxidation 
I - is
L - loss
R - reduction 
I - is
G - gain
35
Q

Reduction definition

A

Reduction - gain of electrons by a reactant.

O - oxidation 
I - is
L - loss
R - reduction 
I - is
G - gain
36
Q

Extraction of metal

A

The higher up a metal is on the electrochemical series, the harder it is to extract the metal from its ore.

During extraction the metal ions are REDUCED to metal atoms.

37
Q

Extracting metals - heat alone

A

Some metals can be extracted from their ore (metal oxide) bu heat alone. This is only the case for the least reactive metals.

  • Silver (Ag)
  • Gold (Au)
  • Mercury (Hg)
38
Q

Extracting metals - heat and carbon

A

The heat and carbon caused the metal to be displaced and the carbon to join up with the oxygen.

The carbon is called a reducing agent.

  • copper (Cu)
  • lead (Pb)
  • iron (Fe)
  • tin (Sn)
  • zinc (Zn)
39
Q

Extracting metals - electrolysis

A

Any metal above aluminium (Al) on the electrochemical series is attracted by electrolysis.

The positive metal ion is attracted to the negative electrode where it gains electrons to turn back into a metal atom.

40
Q

Electrolysis

A

Electrolysis is the process of separating a compound into its elements using electric current.

A D.C. Power supply is used so that the products can be identified and collected.

The negative ions go to the positive electrode.
The positive metal ions go to the negative electrode where they gain electrons and turn back into a metal atom.

Any metal from Al upwards in the E.C.S is extracted by electrolysis.

41
Q

Electrolyte definition

A

Electrolyte is a solution (ionic compound) that contains ions which can conduct electricity.

42
Q

What is needed to make a basic electrochemical cell

A

2 different metals and an electrolyte.

43
Q

What is the use of an ion bridge?

A

The salt/ion bridge is used to complete the circuit by linking the 2 half cells.

44
Q

Voltage - electrochemical series

A

The further apart the metals an the ECS, the greater the voltage that would be produced l.