Unit 2 | Topics: Strength of Acids and Bases, properties of salts, dissociation, polyprotic, leveling effect Flashcards
Comparing Acids
by Ka or pKa, the one higher is the stronger acid
strong acids
perchloric - HClO4
nitric - HNO3
sulfuric - H2SO4
HI, HBr, HCl
Strong bases
LiOH
NaOH
KOH
Ca(OH)2
Sr(OH)2
Ba(OH)2
Case 1: Salts that yield neutral solutions
If both ions are conjugate to a stronge acid or a strong base, then both ions show noa cid-base properties. Ions remain as ions in solution, result in neutral pH
Case 2: Salts that yield weak acidic/basic solutions
If one ion has very weak properties, ie conjugate to a strong acid or a strong base, the other ion is a weak acid or base, then only the weak species is active and determines pH
Case 3: Salts that are both weak acid and bases
if both ions are weak acid/ base, the pH is determined by the species with largest equilibirum constant. determine the acid and base, compare calculated Ka and Kb respectively
weak acid/ base dissociation
- compare K values to determine the dominant source of H3O+/ OH
- make ICE table for dominant rxn
- solve like a small K and do approximations
percent dissociated
amount dissociated/ inital amount x 100