Unit 2 Test Flashcards

1
Q

What are the three steps of refining oil

A

Separation, conversion treating, blending

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2
Q

Explain cracking

A

Long chain alkanes becomes one alkane and two alkenes

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3
Q

What is used up in thermal cracking

A

Heat and pressure

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4
Q

Explain fluid catalytic cracking

A

Gas oil is mixed with powdered catalyst.

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5
Q

Explain hydrocracking

A

Feed is mixed with hydrogen and reactor is filled with fixed bed of catalyst.

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6
Q

What is octane rating

A

Similarity to iso-octane

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7
Q

What is isomerization

A

Platinum is a catalyst to form isomers from alkanes.

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8
Q

What is reforming

A

Aromatic is produced from naphtha vapor

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9
Q

What is alkylation

A

Alkyl group joins an alkene (acid is a catalyst)

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10
Q

What is sweetening

A

Removing sulfur for better smell.

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11
Q

Fluid bed Vs. Fixed Bed

A

Fluid refers to finely powdered while fixed bed refers to small lumps.

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12
Q

What are the two types of catalysts

A

Acids and Solids

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13
Q

What are zeolites made of

A

Zeolites are a mix of silicon, oxygen, and aluminum

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14
Q

What are the characteristics of zeolites

A

They are porous and have a high surface area (900M^2)

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15
Q

What are the benefits of zeolites

A

More active than other catalysts, very durable, very affordable.

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16
Q

What are the two different types of polymerization

A

Addition and condensation

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17
Q

How can you tell if it’s an addition polymerization

A

Two double bonded carbons and two monomers form a polymer.

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18
Q

How can you tell if it’s a condensation polymerization

A

Monomers with functional groups are present on both ends.

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19
Q

What are the three steps in addition polymerization

A

Initiation, propagation, and termination

20
Q

What happens in the initiation stage?

A

A free radical combines with hydrogen peroxide.

21
Q

What happens in the propagation stage

A

More double bonds break.

22
Q

What happens in the termination stage

A

Another free radical joins.

23
Q

HDPE

A

High density polyethylene. Produced with low pressure and is rigid and opaque.

24
Q

LDPE

A

Low density polyethylene. Produced with high pressure, is transparent and weak.

25
List the 5 important monomers in emulsion polymerization
Styrene, Acrylonitrile, 1,3-butadiene, isobutylene, isoprene.
26
Name 3 main emulsion reactions
SBR - (Styrene + Butadiene) Nitrile Rubber (Acrylonitrile + butadiene) Butyl Rubber - Isobutylene + isoprene
27
What is the surfactant molecule
A dispersion agent for monomers and polymers that has a hydrophilic head and hydrophobic tail.
28
What are the three stages of manufacturing rubber
Emulsion polymerization, coagulation, compounding
29
What is emulsion polymerization
Monomer and free radical are emulsified by using surfactants to produce latex.
30
Explain coagulation
- Acidified brine solution breaks emulsion - Synerizing heats to soft - Crumbs pass through vibrating screen to become 0.75% moisture
31
What is the most popular compounding device
Banbury mixer
32
What is compounding
The addition of ingredients to rubber in order to make it higher quality. This includes vulcanization agents, antioxidants, fillers, and carbon black.
33
What is vulcanization
Heating rubber with sulfur.
34
What is the largest produced rubber in the world.
Styrene-butadiene
35
Pollution stats
Plastic takes 500-1,000 years to decompose and there will be more plastic than fish in the ocean by 2050
35
How is styrene-butadiene made
Butadiene and styrene are mixed with surfactant catalysts in an agitated pressure vessel. Once stopped, antioxidant is added.
36
What is oxidation
Loss of electrons
37
What is reduction
Gain of electrons
38
What is Oxygen charge in covalent
-2
39
What is hydrogen charge in covalent
+1
40
What is corrosion
Metals are oxidized by environment
41
How is corrosion prevented
Coating the metals
42
What is used in the plants to prevent corrosion
Cathodic protection (Magnesium is more likely to be oxidized)
43
What is natural rubber
Rubber found in a tree in brazil which is extracted under the bark.
44
What are the four types of reactors
Stirred, fixed bed, fluidized bed, tubular