unit 2 organic chemistry and instrumental analysis Flashcards

1
Q

What does molecular orbital theory state

A

Molecular orbital theory states that when any two atomic orbitals meet each other and overlap they will form two new molecular orbitals in which a maximum of 2 electrons can be found

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2
Q

what is molecular orbital theory used to describe

A

Molecular orbital theory is used to describe how atomic orbitals combine when atoms combine to produce molecules

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3
Q

what forms when atomic orbitals combine

A

molecular orbitals

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4
Q

what does The combination of two atomic orbitals result in

A

The combination of two
atomic orbitals results in the formation of a bonding molecular orbital and an antibonding orbital. The bonding molecular orbital encompasses both nuclei.

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5
Q

what is the basis of bonding between atoms

A

The attraction of the
positively charged nuclei and the negatively charged electrons in the bonding molecular
orbital is the basis of bonding between atoms.

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6
Q

what is the maximum number of electrons that each molecular orbital can hold

A

Each molecular orbital can hold a maximum
of two electrons.

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7
Q

In a non-polar covalent bond, what is the bonding molecular orbitals

A

In a non-polar covalent bond, the bonding molecular orbital is symmetrical about the
midpoint between two atoms.

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8
Q

In a polar covalent bond, what is the bonding molecular orbitals

A

Polar covalent bonds result from bonding molecular orbitals that are asymmetric about the midpoint between two atoms.

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9
Q

which atom has the greater share of the bonding electrons

A

The atom with the greater
value for electronegativity has the greater share of the bonding electrons.

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10
Q

In an ionic compound, what is the bonding molecular orbitals

A

Ionic compounds
are an extreme case of asymmetry, with the bonding molecular orbitals being almost
entirely located around just one atom, resulting in the formation of ions.

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11
Q

what is it called when Molecular orbitals that form by end-on overlap of atomic orbitals along the axis of the covalent bond

A

Molecular orbitals that form by end-on overlap of atomic orbitals along the axis of the
covalent bond are called sigma molecular orbitals or sigma bonds.

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12
Q

What are Molecular orbitals that form by side-on overlap of parallel atomic orbitals that lie perpendicular to the axis of the covalent bond called

A

Molecular orbitals that form by side-on overlap of parallel atomic orbitals that lie perpendicular to the axis of the covalent bond are called pi molecular orbitals or pi bonds.

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13
Q

what can the bonding and shape of carbon molecules be explained by

A

The bonding and shape of molecules of
carbon can be explained by hybridisation.

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14
Q

still in progress

A
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