Unit 2 Glossary Flashcards

1
Q

What is a buffer solution

A

A solution in which the pH remains approximately constant when small amount of acid or base or added

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2
Q

What is a closed system

A

A close system has no exchange of matter energy with its surroundings

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3
Q

What is a conjugate acid

A

For every base there is a conjugate acid formed by the gain of a proton H+

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4
Q

What is a conjugate base

A

For every acid there is a conjugate based formed by the loss of a proton H+

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5
Q

Define diprotic

A

An acid which is able to produce two hydrogen ions from each molecule

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6
Q

What is a dynamic equilibrium

A

I do not like Aqualibrium is achieved when the rate of two opposing processes become equal so that there is no net change results

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7
Q

What is an endpoint

A

The endpoint of a titration is the point at which the reaction is shown to be complete this is the frequency signalled by the change in colour of an indicator

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8
Q

Define entropy

A

The entropy of a system is the degree of disorder in the system the greater this order the greater the entropy Low entropy is associated with strongly ordered substances

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9
Q

What is an equivalence point

A

The equivalence point in a titration experiment is reached when the reaction between a titrant and a titrate is complete

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10
Q

What is the first law of thermodynamics

A

It states that the total energy of the universe is constant energy can neither be created nor destroyed

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11
Q

Define Gibbs standard free energy

A

The standard Gibbs free energy change for a reaction is related to the standard enthalpy and entropy changes

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12
Q

Define Hess’s law

A

States that the overall reaction and to be in the sum of a reaction in selfies of each step of a reaction

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13
Q

What is mean bond enthalpy

A

An average value that is quoted for a bond that can occur in different molecular environments

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14
Q

Define mono Protic

A

An acid which is able to produce one hydrogen iron from each molecule

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15
Q

What is the order of a reaction

A

The power to which the concentration of a particular reactant is raised in the rate equation

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16
Q

What is the overall order of a reaction

A

The sun of the powers to which the concentration of all reactants are raised in the rate equation

17
Q

What is a quantitative reaction

A

Ali’s one where the reactants react completely according to ratios in the balanced stoochiometric equation

18
Q

What is the rate constant

A

K is the rate constant and has a constant value for a given reaction at a particular temperature

19
Q

What is the rate determining step

A

The slowest step in the reaction which governs the overall rate

20
Q

What is the rate equation

A

An equation that displays how the reaction rate depends on concentration of each reactant

21
Q

What is a reaction mechanism

A

The series of simple steps by which a chemical reaction occurs

22
Q

What is the second law of thermodynamics

A

The total entopry of surroundings always increases for a spontaneous change

23
Q

What is standard entholpy change

A

The entholpy change for a reaction in which reactants and products are considered to be in their standard states at a specified temperature

24
Q

What is standards entholpy of combustion

A

The entholpy change that occurs when one mole of a substance is produced from its elements in their standard states

25
Q

What is a standard solution

A

A solution with an accurately known concentration. It can be prepared by weighing a primary standard and dissolving it in a known volume of solution or by titrating against another standard solution

26
Q

What is standard state

A

The most stable state of a substance out element under standard conditions

27
Q

What is the third law of thermodynamics

A

The entropy of a perfect crystal at zero Calvin zero